Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines
The catalytic hydroamination of alkenes provides an efficient and direct entry to synthetically useful amines. An efficient method for the hydroamination between non-activated alkenes and aniline catalyzed by the system of Pr(OTf)3/n-Bu4PI/I2 was developed. Allylamines are important building blocks...
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| Format: | Thesis |
| Language: | English |
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2012
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| Online Access: | https://hdl.handle.net/10356/48065 |