Gold-catalyzed 1,n-enyne cycloisomerizations as synthetic strategies to nitrogen heterocycles

The work in this thesis was undertaken in Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences in Nanyang Technological University from January 2010 to December 2011 under the supervision of Asst Prof Philip Wai Hong Chan. The work of this thesis has been directed toward...

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Main Author: Huang, Chuhui
Other Authors: Philip Wai Hong Chan
Format: Thesis
Language:English
Published: 2012
Subjects:
Online Access:http://hdl.handle.net/10356/48686
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author Huang, Chuhui
author2 Philip Wai Hong Chan
author_facet Philip Wai Hong Chan
Huang, Chuhui
author_sort Huang, Chuhui
collection NTU
description The work in this thesis was undertaken in Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences in Nanyang Technological University from January 2010 to December 2011 under the supervision of Asst Prof Philip Wai Hong Chan. The work of this thesis has been directed toward the efficient synthesis of 1,7-enyne and its application towards nitrogen heterocycles synthesis via gold-catalyzed 1,7-enyne cycloisomerization. This thesis is divided into four chapters: • Chapter I consists of an introduction of gold-catalyzed cycloisomerizations of 1,n-enynes. • Chapter II describes the work on the efficient synthesis of nitrogen heterocycles via sequential iron- and gold-mediated ring-opening and cycloisomerization of cyclopropyl carbinols with aryl sulfonamides. • Chapter III contains the supporting informations were attached for the work described above. • Chapter IV contains references pertaining to this thesis.
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spelling ntu-10356/486862023-02-28T23:38:53Z Gold-catalyzed 1,n-enyne cycloisomerizations as synthetic strategies to nitrogen heterocycles Huang, Chuhui Philip Wai Hong Chan School of Physical and Mathematical Sciences DRNTU::Science::Chemistry The work in this thesis was undertaken in Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences in Nanyang Technological University from January 2010 to December 2011 under the supervision of Asst Prof Philip Wai Hong Chan. The work of this thesis has been directed toward the efficient synthesis of 1,7-enyne and its application towards nitrogen heterocycles synthesis via gold-catalyzed 1,7-enyne cycloisomerization. This thesis is divided into four chapters: • Chapter I consists of an introduction of gold-catalyzed cycloisomerizations of 1,n-enynes. • Chapter II describes the work on the efficient synthesis of nitrogen heterocycles via sequential iron- and gold-mediated ring-opening and cycloisomerization of cyclopropyl carbinols with aryl sulfonamides. • Chapter III contains the supporting informations were attached for the work described above. • Chapter IV contains references pertaining to this thesis. Master of Science 2012-05-08T03:06:50Z 2012-05-08T03:06:50Z 2012 2012 Thesis http://hdl.handle.net/10356/48686 en 134 p. application/pdf
spellingShingle DRNTU::Science::Chemistry
Huang, Chuhui
Gold-catalyzed 1,n-enyne cycloisomerizations as synthetic strategies to nitrogen heterocycles
title Gold-catalyzed 1,n-enyne cycloisomerizations as synthetic strategies to nitrogen heterocycles
title_full Gold-catalyzed 1,n-enyne cycloisomerizations as synthetic strategies to nitrogen heterocycles
title_fullStr Gold-catalyzed 1,n-enyne cycloisomerizations as synthetic strategies to nitrogen heterocycles
title_full_unstemmed Gold-catalyzed 1,n-enyne cycloisomerizations as synthetic strategies to nitrogen heterocycles
title_short Gold-catalyzed 1,n-enyne cycloisomerizations as synthetic strategies to nitrogen heterocycles
title_sort gold catalyzed 1 n enyne cycloisomerizations as synthetic strategies to nitrogen heterocycles
topic DRNTU::Science::Chemistry
url http://hdl.handle.net/10356/48686
work_keys_str_mv AT huangchuhui goldcatalyzed1nenynecycloisomerizationsassyntheticstrategiestonitrogenheterocycles