Synthesis and properties of two photochromic dyes

Photochromic dyes have been extensively studied due to their demands and applications especially in the ophthalmic lens industry. Photochromic lenses respond reversibly to the light intensity; darkens with ultraviolet exposure and changes back to its original state with reduced exposure....

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Bibliographic Details
Main Author: Ng, Shihui.
Other Authors: School of Materials Science and Engineering
Format: Final Year Project (FYP)
Language:English
Published: 2012
Subjects:
Online Access:http://hdl.handle.net/10356/48810
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author Ng, Shihui.
author2 School of Materials Science and Engineering
author_facet School of Materials Science and Engineering
Ng, Shihui.
author_sort Ng, Shihui.
collection NTU
description Photochromic dyes have been extensively studied due to their demands and applications especially in the ophthalmic lens industry. Photochromic lenses respond reversibly to the light intensity; darkens with ultraviolet exposure and changes back to its original state with reduced exposure. Two photochromic dyes are synthesized and properties in colour change are observed. Photochromic dyes when exposed to ultraviolet light, it experiences a transformation from its colourless closed form isomer to the coloured opened form isomer. Identification of intermediate products in the synthesis of Dye 1 and 2 are carried out using techniques such as Electrospray ionization mass spectrometry (MS-ESI), Proton Nuclear Magnetic Resonance (H-NMR), Mass Spectrometry Time -of-Flight (MS-TOF). Finally, Ultraviolet-Visible (UV-Vis) Spectroscopy is conducted on both Dye 1 and 2, and properties are observed. However, transition time of the dyes from coloured to its colourless state, need to be shortened for applications.
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spelling ntu-10356/488102023-03-04T15:30:53Z Synthesis and properties of two photochromic dyes Ng, Shihui. School of Materials Science and Engineering Zhang Qichun DRNTU::Engineering::Materials::Photonics and optoelectronics materials Photochromic dyes have been extensively studied due to their demands and applications especially in the ophthalmic lens industry. Photochromic lenses respond reversibly to the light intensity; darkens with ultraviolet exposure and changes back to its original state with reduced exposure. Two photochromic dyes are synthesized and properties in colour change are observed. Photochromic dyes when exposed to ultraviolet light, it experiences a transformation from its colourless closed form isomer to the coloured opened form isomer. Identification of intermediate products in the synthesis of Dye 1 and 2 are carried out using techniques such as Electrospray ionization mass spectrometry (MS-ESI), Proton Nuclear Magnetic Resonance (H-NMR), Mass Spectrometry Time -of-Flight (MS-TOF). Finally, Ultraviolet-Visible (UV-Vis) Spectroscopy is conducted on both Dye 1 and 2, and properties are observed. However, transition time of the dyes from coloured to its colourless state, need to be shortened for applications. Bachelor of Engineering (Materials Engineering) 2012-05-10T01:12:15Z 2012-05-10T01:12:15Z 2012 2012 Final Year Project (FYP) http://hdl.handle.net/10356/48810 en Nanyang Technological University 35 p. application/pdf
spellingShingle DRNTU::Engineering::Materials::Photonics and optoelectronics materials
Ng, Shihui.
Synthesis and properties of two photochromic dyes
title Synthesis and properties of two photochromic dyes
title_full Synthesis and properties of two photochromic dyes
title_fullStr Synthesis and properties of two photochromic dyes
title_full_unstemmed Synthesis and properties of two photochromic dyes
title_short Synthesis and properties of two photochromic dyes
title_sort synthesis and properties of two photochromic dyes
topic DRNTU::Engineering::Materials::Photonics and optoelectronics materials
url http://hdl.handle.net/10356/48810
work_keys_str_mv AT ngshihui synthesisandpropertiesoftwophotochromicdyes