New aspects of phosphirene chemistry
Two methodologies have been tested for the functionalization of phosphirenes. In the first one, the C−Si bond of a 2-silylphosphirene is activated by a substoichiometric quantity of fluoride ion (TBAF) in THF at −78 °C. Using this technique, it is possible to perform a protodesilylation or a functio...
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| Format: | Thesis |
| Language: | English |
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2012
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| Online Access: | https://hdl.handle.net/10356/49976 |