Growth of coral-like PtAu-MnO2 binary nanocomposites on free-standing graphene paper for flexible nonenzymatic glucose sensors.

The growing demand for compact point-of-care medical devices and portable instruments for on-site environmental sampling has stimulated intense research on flexible sensors that can be miniaturized and function under considerable physical deformation. This project reports a new type of flexible elec...

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Bibliographic Details
Main Author: Tan, Liling.
Other Authors: School of Chemical and Biomedical Engineering
Format: Final Year Project (FYP)
Language:English
Published: 2012
Subjects:
Online Access:http://hdl.handle.net/10356/50076
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author Tan, Liling.
author2 School of Chemical and Biomedical Engineering
author_facet School of Chemical and Biomedical Engineering
Tan, Liling.
author_sort Tan, Liling.
collection NTU
description The growing demand for compact point-of-care medical devices and portable instruments for on-site environmental sampling has stimulated intense research on flexible sensors that can be miniaturized and function under considerable physical deformation. This project reports a new type of flexible electrochemical biosensors based on free-standing graphene paper carrying binary nanocomposites of PtAu alloy and MnO2. The coral-like PtAu–MnO2 nanocomposites were grown on the substrate through a one-step template-free electrodeposition, leading to an intimate contact between the PtAu alloy and MnO2 matrix. The flexible electrode exhibited a unique set of structural and electrochemical properties such as better uniformity, larger active surface areas, and faster electron transfer in comparison with the control electrode prepared by tandem growth of MnO2 network and PtAu alloy in two steps. In non-enzymatic amperometric glucose detection, the PtAu–MnO2 binary nanostructure-decorated graphene paper had shown greatly enhanced sensing performance in terms of sensitivity, selectivity, durability, and tolerability to mechanical stress in comparison with control electrodes. The strategy of co-growth of metal and metal oxides on freestanding carbon substrates opens new possibility to develop high-performance flexible electrochemical sensors.
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spelling ntu-10356/500762023-03-03T15:34:53Z Growth of coral-like PtAu-MnO2 binary nanocomposites on free-standing graphene paper for flexible nonenzymatic glucose sensors. Tan, Liling. School of Chemical and Biomedical Engineering Asst Prof Duan Hongwei DRNTU::Science::Medicine::Biosensors The growing demand for compact point-of-care medical devices and portable instruments for on-site environmental sampling has stimulated intense research on flexible sensors that can be miniaturized and function under considerable physical deformation. This project reports a new type of flexible electrochemical biosensors based on free-standing graphene paper carrying binary nanocomposites of PtAu alloy and MnO2. The coral-like PtAu–MnO2 nanocomposites were grown on the substrate through a one-step template-free electrodeposition, leading to an intimate contact between the PtAu alloy and MnO2 matrix. The flexible electrode exhibited a unique set of structural and electrochemical properties such as better uniformity, larger active surface areas, and faster electron transfer in comparison with the control electrode prepared by tandem growth of MnO2 network and PtAu alloy in two steps. In non-enzymatic amperometric glucose detection, the PtAu–MnO2 binary nanostructure-decorated graphene paper had shown greatly enhanced sensing performance in terms of sensitivity, selectivity, durability, and tolerability to mechanical stress in comparison with control electrodes. The strategy of co-growth of metal and metal oxides on freestanding carbon substrates opens new possibility to develop high-performance flexible electrochemical sensors. Bachelor of Engineering (Chemical and Biomolecular Engineering) 2012-05-29T07:47:49Z 2012-05-29T07:47:49Z 2012 2012 Final Year Project (FYP) http://hdl.handle.net/10356/50076 en Nanyang Technological University 79 p. application/pdf
spellingShingle DRNTU::Science::Medicine::Biosensors
Tan, Liling.
Growth of coral-like PtAu-MnO2 binary nanocomposites on free-standing graphene paper for flexible nonenzymatic glucose sensors.
title Growth of coral-like PtAu-MnO2 binary nanocomposites on free-standing graphene paper for flexible nonenzymatic glucose sensors.
title_full Growth of coral-like PtAu-MnO2 binary nanocomposites on free-standing graphene paper for flexible nonenzymatic glucose sensors.
title_fullStr Growth of coral-like PtAu-MnO2 binary nanocomposites on free-standing graphene paper for flexible nonenzymatic glucose sensors.
title_full_unstemmed Growth of coral-like PtAu-MnO2 binary nanocomposites on free-standing graphene paper for flexible nonenzymatic glucose sensors.
title_short Growth of coral-like PtAu-MnO2 binary nanocomposites on free-standing graphene paper for flexible nonenzymatic glucose sensors.
title_sort growth of coral like ptau mno2 binary nanocomposites on free standing graphene paper for flexible nonenzymatic glucose sensors
topic DRNTU::Science::Medicine::Biosensors
url http://hdl.handle.net/10356/50076
work_keys_str_mv AT tanliling growthofcorallikeptaumno2binarynanocompositesonfreestandinggraphenepaperforflexiblenonenzymaticglucosesensors