Processing of nanostructured nickel-based magnetic materials

A systematic investigation into the structure and properties of five commercially available nickel-based soft magnetic materials was carried out. The five systems are Fe23Ni77, Fei6Ni77Cu7, Fei6Ni77Cu5Cr2, Fei6Ni77Mo7 and Fei6Ni77Nb7. These alloy systems were processed by ball milling to obtain t...

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Main Author: School of Materials Science and Engineering
Other Authors: School of Materials Science & Engineering
Format: Research Report
Published: 2008
Subjects:
Online Access:http://hdl.handle.net/10356/5031
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author School of Materials Science and Engineering
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
School of Materials Science and Engineering
author_sort School of Materials Science and Engineering
collection NTU
description A systematic investigation into the structure and properties of five commercially available nickel-based soft magnetic materials was carried out. The five systems are Fe23Ni77, Fei6Ni77Cu7, Fei6Ni77Cu5Cr2, Fei6Ni77Mo7 and Fei6Ni77Nb7. These alloy systems were processed by ball milling to obtain the compound with grain size of several tens of nanometers in length scale. Depending on the exact chemical composition, some amorphous or semi-amorphous phases were deposited at the inter-granular layers as evidenced from the TEM micrographs. As the grain size decreases to several tens of nanometer in scale, results of the ball milled powders showed that the all the five systems exhibited coercivities that increased with grain size, contrary to the random anisotropy model. These were attributed to the internal stress generated from the mechanical forces. Stress-annealed magnets sintered from the alloyed powders showed strong dependency of the anisotropy on grain size where the coercivity decreases with grain size. The effect of alloying elements on the magnetic properties of these nanostructured magnets suggest that it is less significant compared to the effect on grain size. Although the coercivity varies with the alloying elements, the critical factor on its behaviour is dominated by the grain / particle size.
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spelling ntu-10356/50312023-07-08T06:40:10Z Processing of nanostructured nickel-based magnetic materials School of Materials Science and Engineering School of Materials Science & Engineering DRNTU::Engineering::Materials::Magnetic materials A systematic investigation into the structure and properties of five commercially available nickel-based soft magnetic materials was carried out. The five systems are Fe23Ni77, Fei6Ni77Cu7, Fei6Ni77Cu5Cr2, Fei6Ni77Mo7 and Fei6Ni77Nb7. These alloy systems were processed by ball milling to obtain the compound with grain size of several tens of nanometers in length scale. Depending on the exact chemical composition, some amorphous or semi-amorphous phases were deposited at the inter-granular layers as evidenced from the TEM micrographs. As the grain size decreases to several tens of nanometer in scale, results of the ball milled powders showed that the all the five systems exhibited coercivities that increased with grain size, contrary to the random anisotropy model. These were attributed to the internal stress generated from the mechanical forces. Stress-annealed magnets sintered from the alloyed powders showed strong dependency of the anisotropy on grain size where the coercivity decreases with grain size. The effect of alloying elements on the magnetic properties of these nanostructured magnets suggest that it is less significant compared to the effect on grain size. Although the coercivity varies with the alloying elements, the critical factor on its behaviour is dominated by the grain / particle size. 2008-09-17T10:04:56Z 2008-09-17T10:04:56Z 2006 2006 Research Report http://hdl.handle.net/10356/5031 Nanyang Technological University 75 p. application/pdf
spellingShingle DRNTU::Engineering::Materials::Magnetic materials
School of Materials Science and Engineering
Processing of nanostructured nickel-based magnetic materials
title Processing of nanostructured nickel-based magnetic materials
title_full Processing of nanostructured nickel-based magnetic materials
title_fullStr Processing of nanostructured nickel-based magnetic materials
title_full_unstemmed Processing of nanostructured nickel-based magnetic materials
title_short Processing of nanostructured nickel-based magnetic materials
title_sort processing of nanostructured nickel based magnetic materials
topic DRNTU::Engineering::Materials::Magnetic materials
url http://hdl.handle.net/10356/5031
work_keys_str_mv AT schoolofmaterialsscienceandengineering processingofnanostructurednickelbasedmagneticmaterials