Dry adhesive surfaces based on high density, high aspect ratio, hierarchical polymeric nano-structures

Gecko’s dry attachment system has been acknowledged to be the most efficient among all the biological attachment systems. Many attempts have been made to emulate the topographic features of the gecko feet to construct artificial dry adhesive tapes. However, many of the gecko inspired structures prod...

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Bibliographic Details
Main Author: Ho, Audrey Yoke Yee
Other Authors: Isabel Rodriguez
Format: Thesis
Language:English
Published: 2012
Subjects:
Online Access:https://hdl.handle.net/10356/50670
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author Ho, Audrey Yoke Yee
author2 Isabel Rodriguez
author_facet Isabel Rodriguez
Ho, Audrey Yoke Yee
author_sort Ho, Audrey Yoke Yee
collection NTU
description Gecko’s dry attachment system has been acknowledged to be the most efficient among all the biological attachment systems. Many attempts have been made to emulate the topographic features of the gecko feet to construct artificial dry adhesive tapes. However, many of the gecko inspired structures produced consisted of linear structures made in soft polymers with relatively low density or low aspect ratio in micron or sub micrometer range. As such, a novel methodology was developed to fabricate hierarchical gecko-inspired dry adhesives consisted of high density, high aspect ratio, hierarchical nano-pillars made on a stiff polymeric material. A method is developed for the controlled fabrication of multi-tiered branched porous anodic alumina (PAA). Subsequently, polymeric gecko inspired dry adhesives were produced using the template by a capillary force mediated nano-imprinting. A numerical model was developed for the prediction of the polymer pillar height to obtain the imprinting parameters for complete polymer filling. This model takes into consideration hitherto neglected surface tension effect, a rather important factor for nano-imprinting. Good agreement was obtained between prediction and experimental results. Rigorous characterization of the synthetic dry adhesives’ shear adhesion performance were conducted in both the macro- and micro- scale regimes for a good understanding of the underlying shear adhesion mechanisms.
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spelling ntu-10356/506702023-03-11T17:57:38Z Dry adhesive surfaces based on high density, high aspect ratio, hierarchical polymeric nano-structures Ho, Audrey Yoke Yee Isabel Rodriguez Lam Yee Cheong School of Mechanical and Aerospace Engineering DRNTU::Engineering::Nanotechnology DRNTU::Engineering::Materials::Material testing and characterization Gecko’s dry attachment system has been acknowledged to be the most efficient among all the biological attachment systems. Many attempts have been made to emulate the topographic features of the gecko feet to construct artificial dry adhesive tapes. However, many of the gecko inspired structures produced consisted of linear structures made in soft polymers with relatively low density or low aspect ratio in micron or sub micrometer range. As such, a novel methodology was developed to fabricate hierarchical gecko-inspired dry adhesives consisted of high density, high aspect ratio, hierarchical nano-pillars made on a stiff polymeric material. A method is developed for the controlled fabrication of multi-tiered branched porous anodic alumina (PAA). Subsequently, polymeric gecko inspired dry adhesives were produced using the template by a capillary force mediated nano-imprinting. A numerical model was developed for the prediction of the polymer pillar height to obtain the imprinting parameters for complete polymer filling. This model takes into consideration hitherto neglected surface tension effect, a rather important factor for nano-imprinting. Good agreement was obtained between prediction and experimental results. Rigorous characterization of the synthetic dry adhesives’ shear adhesion performance were conducted in both the macro- and micro- scale regimes for a good understanding of the underlying shear adhesion mechanisms. DOCTOR OF PHILOSOPHY (MAE) 2012-08-27T07:44:07Z 2012-08-27T07:44:07Z 2012 2012 Thesis Ho, A. Y. Y. (2012). Dry adhesive surfaces based on high density, high aspect ratio, hierarchical polymeric nano-structures. Doctoral thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/50670 10.32657/10356/50670 en 288 p. application/pdf
spellingShingle DRNTU::Engineering::Nanotechnology
DRNTU::Engineering::Materials::Material testing and characterization
Ho, Audrey Yoke Yee
Dry adhesive surfaces based on high density, high aspect ratio, hierarchical polymeric nano-structures
title Dry adhesive surfaces based on high density, high aspect ratio, hierarchical polymeric nano-structures
title_full Dry adhesive surfaces based on high density, high aspect ratio, hierarchical polymeric nano-structures
title_fullStr Dry adhesive surfaces based on high density, high aspect ratio, hierarchical polymeric nano-structures
title_full_unstemmed Dry adhesive surfaces based on high density, high aspect ratio, hierarchical polymeric nano-structures
title_short Dry adhesive surfaces based on high density, high aspect ratio, hierarchical polymeric nano-structures
title_sort dry adhesive surfaces based on high density high aspect ratio hierarchical polymeric nano structures
topic DRNTU::Engineering::Nanotechnology
DRNTU::Engineering::Materials::Material testing and characterization
url https://hdl.handle.net/10356/50670
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