Reinforced Hydrogenated Nitrile Butadiene Rubber (HNBR) clay nanocomposites

Nowadays, a rapid and tremendous growth has been seen in the interest of rubber nanocomposite. It has a great potential for novel applications because of the enhancement capability to the base polymer when mixed with small amount of fillers. This is due to the larger interfacial areas per volume tha...

Full description

Bibliographic Details
Main Author: Wangsa, Kelvin Oscar.
Other Authors: Hu Xiao
Format: Final Year Project (FYP)
Language:English
Published: 2013
Subjects:
Online Access:http://hdl.handle.net/10356/51014
_version_ 1824456437552644096
author Wangsa, Kelvin Oscar.
author2 Hu Xiao
author_facet Hu Xiao
Wangsa, Kelvin Oscar.
author_sort Wangsa, Kelvin Oscar.
collection NTU
description Nowadays, a rapid and tremendous growth has been seen in the interest of rubber nanocomposite. It has a great potential for novel applications because of the enhancement capability to the base polymer when mixed with small amount of fillers. This is due to the larger interfacial areas per volume that come in contact with the matrix of base polymer, which results in a greater matrix and filler interaction. Nanocomposites of a type of elastomers called Hydrogenated Nitrile Butadiene Rubber (HNBR) were prepared with reinforcement through nanoclays, and their mechanical properties were investigated. Different loadings of peroxide curing agents and nanoclays were added to HNBR in order to compare their enhancement properties. In addition, “commercial clay” (Montmorillonite Cloisite® 15A) and “treated clay” which is specially treated to promote a stronger interaction between the fillers and the polymer matrix were incorporated into the elastomers to compare their enhancement performance. Moreover, a new technique was also integrated to the experiment in order to promote better dispersion in the polymer matrix that makes a further improvement in mechanical properties. A better mechanical properties as compared to the pure HNBR of Young’s Modulus (increased by ~200%), Tensile Strength (increased by ~800%), and Elongation at Break (increased by ~200%) were observed in 5 wt.% of peroxide curing agents content and mixed with 10 wt.% of treated nanoclays, as compared to other contents variations. Overall, HNBR was successfully reinforced to improve the mechanical properties due to a stronger interaction between the nanoclays and the rubber matrix, and also better filler dispersions in the rubber matrix. In conclusion, this report provides a new way of improvement to reinforce HNBR so that it can be used for more applications that require excellent mechanical properties.
first_indexed 2025-02-19T03:54:05Z
format Final Year Project (FYP)
id ntu-10356/51014
institution Nanyang Technological University
language English
last_indexed 2025-02-19T03:54:05Z
publishDate 2013
record_format dspace
spelling ntu-10356/510142023-03-04T15:39:09Z Reinforced Hydrogenated Nitrile Butadiene Rubber (HNBR) clay nanocomposites Wangsa, Kelvin Oscar. Hu Xiao School of Materials Science and Engineering LANXESS Deutschland GmbH DRNTU::Engineering::Materials::Composite materials Nowadays, a rapid and tremendous growth has been seen in the interest of rubber nanocomposite. It has a great potential for novel applications because of the enhancement capability to the base polymer when mixed with small amount of fillers. This is due to the larger interfacial areas per volume that come in contact with the matrix of base polymer, which results in a greater matrix and filler interaction. Nanocomposites of a type of elastomers called Hydrogenated Nitrile Butadiene Rubber (HNBR) were prepared with reinforcement through nanoclays, and their mechanical properties were investigated. Different loadings of peroxide curing agents and nanoclays were added to HNBR in order to compare their enhancement properties. In addition, “commercial clay” (Montmorillonite Cloisite® 15A) and “treated clay” which is specially treated to promote a stronger interaction between the fillers and the polymer matrix were incorporated into the elastomers to compare their enhancement performance. Moreover, a new technique was also integrated to the experiment in order to promote better dispersion in the polymer matrix that makes a further improvement in mechanical properties. A better mechanical properties as compared to the pure HNBR of Young’s Modulus (increased by ~200%), Tensile Strength (increased by ~800%), and Elongation at Break (increased by ~200%) were observed in 5 wt.% of peroxide curing agents content and mixed with 10 wt.% of treated nanoclays, as compared to other contents variations. Overall, HNBR was successfully reinforced to improve the mechanical properties due to a stronger interaction between the nanoclays and the rubber matrix, and also better filler dispersions in the rubber matrix. In conclusion, this report provides a new way of improvement to reinforce HNBR so that it can be used for more applications that require excellent mechanical properties. Bachelor of Engineering (Materials Engineering) 2013-01-02T09:11:50Z 2013-01-02T09:11:50Z 2012 2012 Final Year Project (FYP) http://hdl.handle.net/10356/51014 en Nanyang Technological University 48 p. application/pdf
spellingShingle DRNTU::Engineering::Materials::Composite materials
Wangsa, Kelvin Oscar.
Reinforced Hydrogenated Nitrile Butadiene Rubber (HNBR) clay nanocomposites
title Reinforced Hydrogenated Nitrile Butadiene Rubber (HNBR) clay nanocomposites
title_full Reinforced Hydrogenated Nitrile Butadiene Rubber (HNBR) clay nanocomposites
title_fullStr Reinforced Hydrogenated Nitrile Butadiene Rubber (HNBR) clay nanocomposites
title_full_unstemmed Reinforced Hydrogenated Nitrile Butadiene Rubber (HNBR) clay nanocomposites
title_short Reinforced Hydrogenated Nitrile Butadiene Rubber (HNBR) clay nanocomposites
title_sort reinforced hydrogenated nitrile butadiene rubber hnbr clay nanocomposites
topic DRNTU::Engineering::Materials::Composite materials
url http://hdl.handle.net/10356/51014
work_keys_str_mv AT wangsakelvinoscar reinforcedhydrogenatednitrilebutadienerubberhnbrclaynanocomposites