Design and development of functional layered double hydroxide nanomaterials for advanced applications.

Layered double hydroxides (LDHs) represent a large important class of anionic clay, which have received increasing attention in many fields owing to their distinguish properties. However, LDHs synthesized by conventional methods are seriously aggregated due to their high charge density of the metal...

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Main Author: Chen, Chunping.
Other Authors: Xu Rong
Format: Thesis
Language:English
Published: 2013
Subjects:
Online Access:http://hdl.handle.net/10356/52423
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author Chen, Chunping.
author2 Xu Rong
author_facet Xu Rong
Chen, Chunping.
author_sort Chen, Chunping.
collection NTU
description Layered double hydroxides (LDHs) represent a large important class of anionic clay, which have received increasing attention in many fields owing to their distinguish properties. However, LDHs synthesized by conventional methods are seriously aggregated due to their high charge density of the metal hydroxide layers. It limits their functionalization and optimum performances in practical applications. The work in this thesis was focused on the synthesis of LDH based nanohybrids and films with good dispersion and order structures, and their functionalization with different properties for advanced applications in environmental and biomedical areas. It includes (a) the design of well-dispersed magnetic-LDH nanohybrids with excellent performance in the treatment of organic dyes; b) fabrication of high quality silver-decorated LDH coating on different substrates for surface antimicrobial application; (c) synthesis of well-dispersed 3D hierarchical LDH spheres for the removal of acidic pharmaceutical pollutants and (d) design of luminescent LDH-drug biovehicles for cancer treatment. It is believed that the findings in this work will greatly contribute towards a better design of functional nanomaterials for wider range of advanced applications.
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spelling ntu-10356/524232023-03-03T16:00:56Z Design and development of functional layered double hydroxide nanomaterials for advanced applications. Chen, Chunping. Xu Rong School of Chemical and Biomedical Engineering DRNTU::Engineering::Chemical engineering Layered double hydroxides (LDHs) represent a large important class of anionic clay, which have received increasing attention in many fields owing to their distinguish properties. However, LDHs synthesized by conventional methods are seriously aggregated due to their high charge density of the metal hydroxide layers. It limits their functionalization and optimum performances in practical applications. The work in this thesis was focused on the synthesis of LDH based nanohybrids and films with good dispersion and order structures, and their functionalization with different properties for advanced applications in environmental and biomedical areas. It includes (a) the design of well-dispersed magnetic-LDH nanohybrids with excellent performance in the treatment of organic dyes; b) fabrication of high quality silver-decorated LDH coating on different substrates for surface antimicrobial application; (c) synthesis of well-dispersed 3D hierarchical LDH spheres for the removal of acidic pharmaceutical pollutants and (d) design of luminescent LDH-drug biovehicles for cancer treatment. It is believed that the findings in this work will greatly contribute towards a better design of functional nanomaterials for wider range of advanced applications. Doctor of Philosophy (SCBE) 2013-05-07T05:03:35Z 2013-05-07T05:03:35Z 2013 2013 Thesis http://hdl.handle.net/10356/52423 en 135 p. application/pdf
spellingShingle DRNTU::Engineering::Chemical engineering
Chen, Chunping.
Design and development of functional layered double hydroxide nanomaterials for advanced applications.
title Design and development of functional layered double hydroxide nanomaterials for advanced applications.
title_full Design and development of functional layered double hydroxide nanomaterials for advanced applications.
title_fullStr Design and development of functional layered double hydroxide nanomaterials for advanced applications.
title_full_unstemmed Design and development of functional layered double hydroxide nanomaterials for advanced applications.
title_short Design and development of functional layered double hydroxide nanomaterials for advanced applications.
title_sort design and development of functional layered double hydroxide nanomaterials for advanced applications
topic DRNTU::Engineering::Chemical engineering
url http://hdl.handle.net/10356/52423
work_keys_str_mv AT chenchunping designanddevelopmentoffunctionallayereddoublehydroxidenanomaterialsforadvancedapplications