Part I: synthesis of azaheterocycles from aryl ketone O-acetyl oximes and internal alkynes by Cu-Rh bimetallic relay catalysts. Part II: Synthesis of 3,4-2H-dihydropyrroles starting from alkenyl carbonitriles and grignard reagents via Cu(II)-mediated iminooxygenation of N-H imines with tempo
Nitrogen-containing heterocycles, also known as azaheterocycles, are important subunits of numerous natural products and are responsible for exhibiting a wide range of biological activities.
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Format: | Thesis |
Language: | English |
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2013
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Online Access: | http://hdl.handle.net/10356/52837 |
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author | Chua, Sze Hui |
author2 | Chiba Shunsuke |
author_facet | Chiba Shunsuke Chua, Sze Hui |
author_sort | Chua, Sze Hui |
collection | NTU |
description | Nitrogen-containing heterocycles, also known as azaheterocycles, are important subunits of numerous natural products and are responsible for exhibiting a wide range of biological activities. |
first_indexed | 2024-10-01T07:57:37Z |
format | Thesis |
id | ntu-10356/52837 |
institution | Nanyang Technological University |
language | English |
last_indexed | 2024-10-01T07:57:37Z |
publishDate | 2013 |
record_format | dspace |
spelling | ntu-10356/528372023-02-28T23:56:14Z Part I: synthesis of azaheterocycles from aryl ketone O-acetyl oximes and internal alkynes by Cu-Rh bimetallic relay catalysts. Part II: Synthesis of 3,4-2H-dihydropyrroles starting from alkenyl carbonitriles and grignard reagents via Cu(II)-mediated iminooxygenation of N-H imines with tempo Chua, Sze Hui Chiba Shunsuke School of Physical and Mathematical Sciences DRNTU::Science::Chemistry Nitrogen-containing heterocycles, also known as azaheterocycles, are important subunits of numerous natural products and are responsible for exhibiting a wide range of biological activities. Master of Science 2013-05-28T04:53:23Z 2013-05-28T04:53:23Z 2012 2012 Thesis http://hdl.handle.net/10356/52837 en 129 p. application/pdf |
spellingShingle | DRNTU::Science::Chemistry Chua, Sze Hui Part I: synthesis of azaheterocycles from aryl ketone O-acetyl oximes and internal alkynes by Cu-Rh bimetallic relay catalysts. Part II: Synthesis of 3,4-2H-dihydropyrroles starting from alkenyl carbonitriles and grignard reagents via Cu(II)-mediated iminooxygenation of N-H imines with tempo |
title | Part I: synthesis of azaheterocycles from aryl ketone O-acetyl oximes and internal alkynes by Cu-Rh bimetallic relay catalysts. Part II: Synthesis of 3,4-2H-dihydropyrroles starting from alkenyl carbonitriles and grignard reagents via Cu(II)-mediated iminooxygenation of N-H imines with tempo |
title_full | Part I: synthesis of azaheterocycles from aryl ketone O-acetyl oximes and internal alkynes by Cu-Rh bimetallic relay catalysts. Part II: Synthesis of 3,4-2H-dihydropyrroles starting from alkenyl carbonitriles and grignard reagents via Cu(II)-mediated iminooxygenation of N-H imines with tempo |
title_fullStr | Part I: synthesis of azaheterocycles from aryl ketone O-acetyl oximes and internal alkynes by Cu-Rh bimetallic relay catalysts. Part II: Synthesis of 3,4-2H-dihydropyrroles starting from alkenyl carbonitriles and grignard reagents via Cu(II)-mediated iminooxygenation of N-H imines with tempo |
title_full_unstemmed | Part I: synthesis of azaheterocycles from aryl ketone O-acetyl oximes and internal alkynes by Cu-Rh bimetallic relay catalysts. Part II: Synthesis of 3,4-2H-dihydropyrroles starting from alkenyl carbonitriles and grignard reagents via Cu(II)-mediated iminooxygenation of N-H imines with tempo |
title_short | Part I: synthesis of azaheterocycles from aryl ketone O-acetyl oximes and internal alkynes by Cu-Rh bimetallic relay catalysts. Part II: Synthesis of 3,4-2H-dihydropyrroles starting from alkenyl carbonitriles and grignard reagents via Cu(II)-mediated iminooxygenation of N-H imines with tempo |
title_sort | part i synthesis of azaheterocycles from aryl ketone o acetyl oximes and internal alkynes by cu rh bimetallic relay catalysts part ii synthesis of 3 4 2h dihydropyrroles starting from alkenyl carbonitriles and grignard reagents via cu ii mediated iminooxygenation of n h imines with tempo |
topic | DRNTU::Science::Chemistry |
url | http://hdl.handle.net/10356/52837 |
work_keys_str_mv | AT chuaszehui partisynthesisofazaheterocyclesfromarylketoneoacetyloximesandinternalalkynesbycurhbimetallicrelaycatalystspartiisynthesisof342hdihydropyrrolesstartingfromalkenylcarbonitrilesandgrignardreagentsviacuiimediatediminooxygenationofnhimineswithtempo |