Ultrafast dynamics of Ag/AgCl as a plasmonic photocatalyst

Plamsmonic photocatalysts have recently garnered much attention due to their enhanced e ciency in converting chemicals to harmless products. Ag/AgCl was the rst of such structure to exhibit the degradation of MO in the presence of visible light1, and since then, many other viable materials...

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Autor principal: Neo, Chee Yong
Outros Autores: Sum Tze Chien
Formato: Final Year Project (FYP)
Idioma:English
Publicado em: 2013
Assuntos:
Acesso em linha:http://hdl.handle.net/10356/53658
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author Neo, Chee Yong
author2 Sum Tze Chien
author_facet Sum Tze Chien
Neo, Chee Yong
author_sort Neo, Chee Yong
collection NTU
description Plamsmonic photocatalysts have recently garnered much attention due to their enhanced e ciency in converting chemicals to harmless products. Ag/AgCl was the rst of such structure to exhibit the degradation of MO in the presence of visible light1, and since then, many other viable materials have seen been discovered2. However, the ultrafast dynamics of such noble metal/semiconductor plasmonic photocatalysts has not been studied by the community. The ability to identify charge carrier dynamics is one of key importance in understanding the characteristics of the material. This study attempts to solve this lack of information by studying how the morphology and the corresponding charge dynamics of a core shell cube of AgCl changes when it is exposed to a laser for more than 12h. From the studies, it is found that Ag structures have formed on the surface due to migration of elemental Ag onto the surface. This change has lead to an ampli cation of the e ects of Ag on the surface of AgCl allowing the study of the charge dynamics of the combined structure. The charge dynamics show results contrary to current proposed mechanics, but further investigation is needed to verify the origin of the charge dynamics observed.
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spelling ntu-10356/536582023-02-28T23:11:09Z Ultrafast dynamics of Ag/AgCl as a plasmonic photocatalyst Neo, Chee Yong Sum Tze Chien School of Physical and Mathematical Sciences DRNTU::Science::Physics::Optics and light Plamsmonic photocatalysts have recently garnered much attention due to their enhanced e ciency in converting chemicals to harmless products. Ag/AgCl was the rst of such structure to exhibit the degradation of MO in the presence of visible light1, and since then, many other viable materials have seen been discovered2. However, the ultrafast dynamics of such noble metal/semiconductor plasmonic photocatalysts has not been studied by the community. The ability to identify charge carrier dynamics is one of key importance in understanding the characteristics of the material. This study attempts to solve this lack of information by studying how the morphology and the corresponding charge dynamics of a core shell cube of AgCl changes when it is exposed to a laser for more than 12h. From the studies, it is found that Ag structures have formed on the surface due to migration of elemental Ag onto the surface. This change has lead to an ampli cation of the e ects of Ag on the surface of AgCl allowing the study of the charge dynamics of the combined structure. The charge dynamics show results contrary to current proposed mechanics, but further investigation is needed to verify the origin of the charge dynamics observed. Bachelor of Science in Physics 2013-06-06T08:18:33Z 2013-06-06T08:18:33Z 2013 2013 Final Year Project (FYP) http://hdl.handle.net/10356/53658 en 53 p. application/pdf
spellingShingle DRNTU::Science::Physics::Optics and light
Neo, Chee Yong
Ultrafast dynamics of Ag/AgCl as a plasmonic photocatalyst
title Ultrafast dynamics of Ag/AgCl as a plasmonic photocatalyst
title_full Ultrafast dynamics of Ag/AgCl as a plasmonic photocatalyst
title_fullStr Ultrafast dynamics of Ag/AgCl as a plasmonic photocatalyst
title_full_unstemmed Ultrafast dynamics of Ag/AgCl as a plasmonic photocatalyst
title_short Ultrafast dynamics of Ag/AgCl as a plasmonic photocatalyst
title_sort ultrafast dynamics of ag agcl as a plasmonic photocatalyst
topic DRNTU::Science::Physics::Optics and light
url http://hdl.handle.net/10356/53658
work_keys_str_mv AT neocheeyong ultrafastdynamicsofagagclasaplasmonicphotocatalyst