Surface modification of TiO2 nanostructures for visible light photocatalyst

In this project, we studied the methods to improve the photocatalytic efficiency of TiO2 nanostructures in pollutant degradation and elimination. From researches done over years, it is proven that TiO2 is one of the most prominent oxides for photo catalyst. However, not many studies have be...

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Bibliographic Details
Main Author: Chen, Jia.
Other Authors: Tan Ooi Kiang
Format: Final Year Project (FYP)
Language:English
Published: 2013
Subjects:
Online Access:http://hdl.handle.net/10356/54259
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author Chen, Jia.
author2 Tan Ooi Kiang
author_facet Tan Ooi Kiang
Chen, Jia.
author_sort Chen, Jia.
collection NTU
description In this project, we studied the methods to improve the photocatalytic efficiency of TiO2 nanostructures in pollutant degradation and elimination. From researches done over years, it is proven that TiO2 is one of the most prominent oxides for photo catalyst. However, not many studies have been conducted on nanotubes with branched microstructures. Although nano-sized TiO2 is environmental friendly and cost effective in terms of photo catalyst performances, its efficiency is low. The main barrier lies within the issues of quick recombination of electrons, holes pairs and poor absorbance of visible light. It was shown that TiO2 exhibits photo catalytic behaviour under UV light, but UV light merely takes up about 4% of the sunlight, but visible light takes up around half. Hence, extension of the absorption spectrum for TiO2 after surface modification is one key parameters of our interest. In this project, TiO2 nanorod arrays have been grown on the glass substrates by hydrothermal growth and were converted into TiO2 nanotube arrays by hydrothermal etching to increase the surface area further. Ag3PO4 were deposited on the surface of the TiO2 nanorods and nanotubes and the photocatalytic properties have been enhanced by the Ag3PO4 surface modification. Ag dopants act as electron sinks and can increase electron/hole lifetime. Moreover, sinks would be aiding electron-hole separation
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spelling ntu-10356/542592023-07-07T15:52:03Z Surface modification of TiO2 nanostructures for visible light photocatalyst Chen, Jia. Tan Ooi Kiang School of Electrical and Electronic Engineering DRNTU::Engineering In this project, we studied the methods to improve the photocatalytic efficiency of TiO2 nanostructures in pollutant degradation and elimination. From researches done over years, it is proven that TiO2 is one of the most prominent oxides for photo catalyst. However, not many studies have been conducted on nanotubes with branched microstructures. Although nano-sized TiO2 is environmental friendly and cost effective in terms of photo catalyst performances, its efficiency is low. The main barrier lies within the issues of quick recombination of electrons, holes pairs and poor absorbance of visible light. It was shown that TiO2 exhibits photo catalytic behaviour under UV light, but UV light merely takes up about 4% of the sunlight, but visible light takes up around half. Hence, extension of the absorption spectrum for TiO2 after surface modification is one key parameters of our interest. In this project, TiO2 nanorod arrays have been grown on the glass substrates by hydrothermal growth and were converted into TiO2 nanotube arrays by hydrothermal etching to increase the surface area further. Ag3PO4 were deposited on the surface of the TiO2 nanorods and nanotubes and the photocatalytic properties have been enhanced by the Ag3PO4 surface modification. Ag dopants act as electron sinks and can increase electron/hole lifetime. Moreover, sinks would be aiding electron-hole separation Bachelor of Engineering 2013-06-18T03:14:03Z 2013-06-18T03:14:03Z 2013 2013 Final Year Project (FYP) http://hdl.handle.net/10356/54259 en Nanyang Technological University 57 p. application/pdf application/pdf
spellingShingle DRNTU::Engineering
Chen, Jia.
Surface modification of TiO2 nanostructures for visible light photocatalyst
title Surface modification of TiO2 nanostructures for visible light photocatalyst
title_full Surface modification of TiO2 nanostructures for visible light photocatalyst
title_fullStr Surface modification of TiO2 nanostructures for visible light photocatalyst
title_full_unstemmed Surface modification of TiO2 nanostructures for visible light photocatalyst
title_short Surface modification of TiO2 nanostructures for visible light photocatalyst
title_sort surface modification of tio2 nanostructures for visible light photocatalyst
topic DRNTU::Engineering
url http://hdl.handle.net/10356/54259
work_keys_str_mv AT chenjia surfacemodificationoftio2nanostructuresforvisiblelightphotocatalyst