Developing high-performance enzymatic biofuel cell

Nowadays, biomaterials is becoming a promising green and renewable technology compared with conventional fossil fuels. It occurs either in forms of biofuels, which is a process of converting chemical energy in the substances into mechanical energies, or biofuel cells (BFCs), which use enzymes as the...

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Bibliographic Details
Main Author: Yan, Ruyu
Other Authors: Chen Peng
Format: Thesis
Language:English
Published: 2013
Subjects:
Online Access:http://hdl.handle.net/10356/54354
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author Yan, Ruyu
author2 Chen Peng
author_facet Chen Peng
Yan, Ruyu
author_sort Yan, Ruyu
collection NTU
description Nowadays, biomaterials is becoming a promising green and renewable technology compared with conventional fossil fuels. It occurs either in forms of biofuels, which is a process of converting chemical energy in the substances into mechanical energies, or biofuel cells (BFCs), which use enzymes as the catalysts to harvest energy from environmental and sustainable fuels abundantly producible from biological systems. However, the applications of current BFCs is greatly limited by their poor stability and high specificity to only one fuel type of these bio-catalysts. In this project, we demonstrate a unique BFC equipped with two identical enzyme-free electrodes based on Co3O4 coated 3D graphene, has the ability to harvest electricity from various sugarfuels (glucose, sucrose, or lactose) efficiently. Considering the advantages of the dual catalytic ability of nanostructured Co3O4 for both glucose oxidation and oxygen reduction together with the exceptional electrical and structural properties of 3D graphene, our glucose-powered BFC which has the excellent long-term stability, can provide the highest open circuit potential (~1.1 V) and power density output (2.38 ± 0.17 mW/cm2) ever reported.
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spelling ntu-10356/543542023-03-03T16:04:53Z Developing high-performance enzymatic biofuel cell Yan, Ruyu Chen Peng School of Chemical and Biomedical Engineering DRNTU::Engineering::Bioengineering Nowadays, biomaterials is becoming a promising green and renewable technology compared with conventional fossil fuels. It occurs either in forms of biofuels, which is a process of converting chemical energy in the substances into mechanical energies, or biofuel cells (BFCs), which use enzymes as the catalysts to harvest energy from environmental and sustainable fuels abundantly producible from biological systems. However, the applications of current BFCs is greatly limited by their poor stability and high specificity to only one fuel type of these bio-catalysts. In this project, we demonstrate a unique BFC equipped with two identical enzyme-free electrodes based on Co3O4 coated 3D graphene, has the ability to harvest electricity from various sugarfuels (glucose, sucrose, or lactose) efficiently. Considering the advantages of the dual catalytic ability of nanostructured Co3O4 for both glucose oxidation and oxygen reduction together with the exceptional electrical and structural properties of 3D graphene, our glucose-powered BFC which has the excellent long-term stability, can provide the highest open circuit potential (~1.1 V) and power density output (2.38 ± 0.17 mW/cm2) ever reported. ​Master of Science (Biomedical Engineering) 2013-06-19T06:16:04Z 2013-06-19T06:16:04Z 2013 2013 Thesis http://hdl.handle.net/10356/54354 en 61 p. application/pdf
spellingShingle DRNTU::Engineering::Bioengineering
Yan, Ruyu
Developing high-performance enzymatic biofuel cell
title Developing high-performance enzymatic biofuel cell
title_full Developing high-performance enzymatic biofuel cell
title_fullStr Developing high-performance enzymatic biofuel cell
title_full_unstemmed Developing high-performance enzymatic biofuel cell
title_short Developing high-performance enzymatic biofuel cell
title_sort developing high performance enzymatic biofuel cell
topic DRNTU::Engineering::Bioengineering
url http://hdl.handle.net/10356/54354
work_keys_str_mv AT yanruyu developinghighperformanceenzymaticbiofuelcell