Part I : Synthesis of azaheterocycles from aryl ketone o-acetyl oximes and internal alkynes by Cu-Rh bimetallic relay catalysts. Part II: Synthesis of 3,4-2h-dihydropyrroles starting from alkenyl carbonitriles and grignard reagents via cu(ii)-mediated iminooxygenation of N-H imines with tempo.

Nitrogen-containing heterocycles, also known as azaheterocycles, are important subunits of numerous natural products and are responsible for exhibiting a wide range of biological activities.

Bibliographic Details
Main Author: Chua, Sze Hui
Other Authors: Chiba Shunsuke
Format: Thesis
Language:English
Published: 2013
Subjects:
Online Access:http://hdl.handle.net/10356/54685
Description
Summary:Nitrogen-containing heterocycles, also known as azaheterocycles, are important subunits of numerous natural products and are responsible for exhibiting a wide range of biological activities.