Chemistry of base-stabilized group 14 element (I) dimers
This thesis describes the reactivity studies of an amidinate-stabilized silicon(I) dimer [LSi:-Si:L] (L = PhC(NtBu)2). The synthesis, characterization and theoretical studies of the first examples of heavier group 14 cyclobutadiene analogues which comprise of heavier group 14 elements, silicon, germ...
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| Формат: | Диссертация |
| Язык: | English |
| Опубликовано: |
2014
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| Online-ссылка: | https://hdl.handle.net/10356/55296 |
| _version_ | 1826110803283017728 |
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| author | Yeong, Crystal Huixian |
| author2 | So Cheuk Wai |
| author_facet | So Cheuk Wai Yeong, Crystal Huixian |
| author_sort | Yeong, Crystal Huixian |
| collection | NTU |
| description | This thesis describes the reactivity studies of an amidinate-stabilized silicon(I) dimer [LSi:-Si:L] (L = PhC(NtBu)2). The synthesis, characterization and theoretical studies of the first examples of heavier group 14 cyclobutadiene analogues which comprise of heavier group 14 elements, silicon, germanium and tin, in the four-membered skeleton are also described. Additionally, the synthesis and reactivity of an amidinate-stabilized silyliumylidene cation [LSi(DMAP)]OTf is described. Lastly, the synthesis and characterization of a germanium(I) dimer and a germylidenide anion stabilized by the 2-imino-5,6-methylenedioxylphenyl ligand is described. |
| first_indexed | 2024-10-01T02:40:28Z |
| format | Thesis |
| id | ntu-10356/55296 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T02:40:28Z |
| publishDate | 2014 |
| record_format | dspace |
| spelling | ntu-10356/552962023-02-28T23:33:08Z Chemistry of base-stabilized group 14 element (I) dimers Yeong, Crystal Huixian So Cheuk Wai School of Physical and Mathematical Sciences DRNTU::Science::Chemistry This thesis describes the reactivity studies of an amidinate-stabilized silicon(I) dimer [LSi:-Si:L] (L = PhC(NtBu)2). The synthesis, characterization and theoretical studies of the first examples of heavier group 14 cyclobutadiene analogues which comprise of heavier group 14 elements, silicon, germanium and tin, in the four-membered skeleton are also described. Additionally, the synthesis and reactivity of an amidinate-stabilized silyliumylidene cation [LSi(DMAP)]OTf is described. Lastly, the synthesis and characterization of a germanium(I) dimer and a germylidenide anion stabilized by the 2-imino-5,6-methylenedioxylphenyl ligand is described. DOCTOR OF PHILOSOPHY (SPMS) 2014-01-28T08:47:35Z 2014-01-28T08:47:35Z 2014 2014 Thesis Yeong, C. H. (2014). Chemistry of base-stabilized group 14 element(I) dimers. Doctoral thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/55296 10.32657/10356/55296 en 155 p. application/pdf |
| spellingShingle | DRNTU::Science::Chemistry Yeong, Crystal Huixian Chemistry of base-stabilized group 14 element (I) dimers |
| title | Chemistry of base-stabilized group 14 element (I) dimers |
| title_full | Chemistry of base-stabilized group 14 element (I) dimers |
| title_fullStr | Chemistry of base-stabilized group 14 element (I) dimers |
| title_full_unstemmed | Chemistry of base-stabilized group 14 element (I) dimers |
| title_short | Chemistry of base-stabilized group 14 element (I) dimers |
| title_sort | chemistry of base stabilized group 14 element i dimers |
| topic | DRNTU::Science::Chemistry |
| url | https://hdl.handle.net/10356/55296 |
| work_keys_str_mv | AT yeongcrystalhuixian chemistryofbasestabilizedgroup14elementidimers |