Part 1: Synthesis of vinyl sulfones via palladium-catalyzed sulfonylation of olefins. Part 2: Trienes : Synthesis via C-H Functionalization and as precursors to complex molecules.
In Part 1, we would like to introduce a new protocol for the synthesis of vinyl sulfones via palladium-catalyzed sulfonylation of olefins using Pd(PhCN)2Cl2 (10 mol%) as a catalyst and K2CO3 (0.5 equiv) in dioxane. Both vinyl-pyridine and enamides were able to afford the corresponding products in mo...
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| Format: | Thesis |
| Language: | English |
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2014
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| Online Access: | http://hdl.handle.net/10356/55385 |