High-performance asymmetric supercapacitor based on graphene hydrogel-nickel composite and manganese (II) oxide-nickel hybrid

Supercapacitors have emerged with the potential to enable major advances in energy storage. Literatures have shown that they have a number of important features including fast charging/discharging rate, excellent cycle stability, long shelf live and are environmentally friendly. As a result, superca...

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Main Author: Chow, Jian You
Other Authors: Duan HongWei
Format: Final Year Project (FYP)
Language:English
Published: 2014
Subjects:
Online Access:http://hdl.handle.net/10356/60238
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author Chow, Jian You
author2 Duan HongWei
author_facet Duan HongWei
Chow, Jian You
author_sort Chow, Jian You
collection NTU
description Supercapacitors have emerged with the potential to enable major advances in energy storage. Literatures have shown that they have a number of important features including fast charging/discharging rate, excellent cycle stability, long shelf live and are environmentally friendly. As a result, supercapacitors may become an attractive power solution for an increasing number of applications. In this report, the performance of a type of supercapacitor, hydrid (asymmetric) capacitor will be evaluated. In theory by utilizing two different composite materials in each electrode, namely the Graphene Hydrogel - Nickel Foam (GH-NF) as the negative electrode and Manganese Dioxide-Nickel Foam ( MnO2-NF) as the positive electrode, the hybrid supercapacitor with an asymmetric electrode configuration will be able capitalise on both electrode materials' advantages in improving overall cell voltage, energy and power densities. Various electrochemical tests such as Cyclic Voltammetry (CV), Galvanostatic Charge-Discharge (GCD) techniques and characterisation test such as field emission scanning electron microscopy (FESEM) have been used to evaluate their performance. The asymmetric supecapacitor could cycle reversibly in a voltage of 0-2.0 V and gives an energy and power densities of 16.06kWh/kg and 2kW/kg respectively. Moreover, the asymmetric supercapacitor exhibit excellent cycle stability, and the capacitance retention of the asymmetrical supercapacitor is 81% after repeating the GCD test at a constant rate of 2A/g for 5000 cycles.
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spelling ntu-10356/602382023-03-03T15:32:22Z High-performance asymmetric supercapacitor based on graphene hydrogel-nickel composite and manganese (II) oxide-nickel hybrid Chow, Jian You Duan HongWei School of Chemical and Biomedical Engineering DRNTU::Engineering::Nanotechnology Supercapacitors have emerged with the potential to enable major advances in energy storage. Literatures have shown that they have a number of important features including fast charging/discharging rate, excellent cycle stability, long shelf live and are environmentally friendly. As a result, supercapacitors may become an attractive power solution for an increasing number of applications. In this report, the performance of a type of supercapacitor, hydrid (asymmetric) capacitor will be evaluated. In theory by utilizing two different composite materials in each electrode, namely the Graphene Hydrogel - Nickel Foam (GH-NF) as the negative electrode and Manganese Dioxide-Nickel Foam ( MnO2-NF) as the positive electrode, the hybrid supercapacitor with an asymmetric electrode configuration will be able capitalise on both electrode materials' advantages in improving overall cell voltage, energy and power densities. Various electrochemical tests such as Cyclic Voltammetry (CV), Galvanostatic Charge-Discharge (GCD) techniques and characterisation test such as field emission scanning electron microscopy (FESEM) have been used to evaluate their performance. The asymmetric supecapacitor could cycle reversibly in a voltage of 0-2.0 V and gives an energy and power densities of 16.06kWh/kg and 2kW/kg respectively. Moreover, the asymmetric supercapacitor exhibit excellent cycle stability, and the capacitance retention of the asymmetrical supercapacitor is 81% after repeating the GCD test at a constant rate of 2A/g for 5000 cycles. Bachelor of Engineering (Chemical and Biomolecular Engineering) 2014-05-26T03:35:23Z 2014-05-26T03:35:23Z 2014 2014 Final Year Project (FYP) http://hdl.handle.net/10356/60238 en Nanyang Technological University 59 p. application/pdf
spellingShingle DRNTU::Engineering::Nanotechnology
Chow, Jian You
High-performance asymmetric supercapacitor based on graphene hydrogel-nickel composite and manganese (II) oxide-nickel hybrid
title High-performance asymmetric supercapacitor based on graphene hydrogel-nickel composite and manganese (II) oxide-nickel hybrid
title_full High-performance asymmetric supercapacitor based on graphene hydrogel-nickel composite and manganese (II) oxide-nickel hybrid
title_fullStr High-performance asymmetric supercapacitor based on graphene hydrogel-nickel composite and manganese (II) oxide-nickel hybrid
title_full_unstemmed High-performance asymmetric supercapacitor based on graphene hydrogel-nickel composite and manganese (II) oxide-nickel hybrid
title_short High-performance asymmetric supercapacitor based on graphene hydrogel-nickel composite and manganese (II) oxide-nickel hybrid
title_sort high performance asymmetric supercapacitor based on graphene hydrogel nickel composite and manganese ii oxide nickel hybrid
topic DRNTU::Engineering::Nanotechnology
url http://hdl.handle.net/10356/60238
work_keys_str_mv AT chowjianyou highperformanceasymmetricsupercapacitorbasedongraphenehydrogelnickelcompositeandmanganeseiioxidenickelhybrid