Rapid detection of heavy metals in incineration bottom ash

This project serves to develop a means for rapid detection of heavy metals in incineration bottom ash, allowing for rapid characterisation of it for utilisation or recycle for other applications. The focus of this project was divided into two general sections. The first part was to develop a means t...

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Detalhes bibliográficos
Autor principal: Koh, Edwin Fang Kai
Outros Autores: Wang Jing Yuan
Formato: Final Year Project (FYP)
Idioma:English
Publicado em: 2015
Assuntos:
Acesso em linha:http://hdl.handle.net/10356/64206
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author Koh, Edwin Fang Kai
author2 Wang Jing Yuan
author_facet Wang Jing Yuan
Koh, Edwin Fang Kai
author_sort Koh, Edwin Fang Kai
collection NTU
description This project serves to develop a means for rapid detection of heavy metals in incineration bottom ash, allowing for rapid characterisation of it for utilisation or recycle for other applications. The focus of this project was divided into two general sections. The first part was to develop a means to reduce the time required for toxicity characteristic leaching procedure (TCLP). This was achieved through the use of sonochemistry to speed up the ±18hours extraction period required in a method labelled as sonoleaching. Preliminary investigations have shown that sonoleaching is indeed an effective method for the leaching of heavy metals. However, there were further studies required in order to better match the results from TCLP. The second part of the project was focused on the analysis of heavy metals from leachates obtained. This was done using electrochemistry or to be more precise the use of square wave anodic stripping voltammetry (SWASV) and screen printed electrodes manufactured by Drop Sens. Out of the different types of electrodes studied the carbon electrode (DRP-110) has been found to be most effective in the rapid detection of heavy metals and also was most financially viable. The results indicated that the electrode in question was able to detect Zn, Pb and Cd simultaneously allowing for a well-defined calibration curve to be established from standard mixtures. Overall, the integration of sonoleaching and electrochemical detection yields positive results. The advent of sonoleaching was able to greatly reduce the leaching time required. The combination of these two methods provided a feasible system for the detection of heavy metals on site. Nonetheless, further studies are required to better match the TCLP results with ultrasonic methods. Also, better understanding of various disturbances to electrochemical detection needs to be studied in greater detail before the system can be established
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spelling ntu-10356/642062023-03-03T17:24:45Z Rapid detection of heavy metals in incineration bottom ash Koh, Edwin Fang Kai Wang Jing Yuan School of Civil and Environmental Engineering Nanyang Environment and Water Research Institute DRNTU::Engineering::Civil engineering This project serves to develop a means for rapid detection of heavy metals in incineration bottom ash, allowing for rapid characterisation of it for utilisation or recycle for other applications. The focus of this project was divided into two general sections. The first part was to develop a means to reduce the time required for toxicity characteristic leaching procedure (TCLP). This was achieved through the use of sonochemistry to speed up the ±18hours extraction period required in a method labelled as sonoleaching. Preliminary investigations have shown that sonoleaching is indeed an effective method for the leaching of heavy metals. However, there were further studies required in order to better match the results from TCLP. The second part of the project was focused on the analysis of heavy metals from leachates obtained. This was done using electrochemistry or to be more precise the use of square wave anodic stripping voltammetry (SWASV) and screen printed electrodes manufactured by Drop Sens. Out of the different types of electrodes studied the carbon electrode (DRP-110) has been found to be most effective in the rapid detection of heavy metals and also was most financially viable. The results indicated that the electrode in question was able to detect Zn, Pb and Cd simultaneously allowing for a well-defined calibration curve to be established from standard mixtures. Overall, the integration of sonoleaching and electrochemical detection yields positive results. The advent of sonoleaching was able to greatly reduce the leaching time required. The combination of these two methods provided a feasible system for the detection of heavy metals on site. Nonetheless, further studies are required to better match the TCLP results with ultrasonic methods. Also, better understanding of various disturbances to electrochemical detection needs to be studied in greater detail before the system can be established Bachelor of Engineering (Environmental Engineering) 2015-05-25T06:25:57Z 2015-05-25T06:25:57Z 2015 2015 Final Year Project (FYP) http://hdl.handle.net/10356/64206 en Nanyang Technological University 52 p. application/pdf
spellingShingle DRNTU::Engineering::Civil engineering
Koh, Edwin Fang Kai
Rapid detection of heavy metals in incineration bottom ash
title Rapid detection of heavy metals in incineration bottom ash
title_full Rapid detection of heavy metals in incineration bottom ash
title_fullStr Rapid detection of heavy metals in incineration bottom ash
title_full_unstemmed Rapid detection of heavy metals in incineration bottom ash
title_short Rapid detection of heavy metals in incineration bottom ash
title_sort rapid detection of heavy metals in incineration bottom ash
topic DRNTU::Engineering::Civil engineering
url http://hdl.handle.net/10356/64206
work_keys_str_mv AT kohedwinfangkai rapiddetectionofheavymetalsinincinerationbottomash