Synthesis of azaheterocycles by Cu-catalyzed aerobic alkene diamination and tempo-mediated aliphatic C-H oxidation

Synthesis of azaheterocycles by Cu-catalyzed aerobic alkene diamination and tempo-mediated aliphatic C-H oxidation

Due to the significance of nitrogen-containing heterocycles (azaheterocycles) in biology, medicine and materials science, it is important to invent robust methodologies for synthesis of azaheterocycles using readily available nitrogen-containing starting materials in unprecedented fashions. This the...

Disgrifiad llawn

Manylion Llyfryddiaeth
Prif Awdur:	Zhu, Xu
Awduron Eraill:	Chiba Shunsuke
Fformat:	Traethawd Ymchwil
Iaith:	English
Cyhoeddwyd:	2015
Pynciau:	DRNTU::Science::Chemistry
Mynediad Ar-lein:	http://hdl.handle.net/10356/65740

Eitemau Tebyg

Cu-Catalyzed aerobic molecular transformation of imine and enamine derivatives for synthesis of Azaheterocycles
gan: Chiba, Shunsuke
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TEMPO-mediated aliphatic C–H oxidation with oximes and hydrazones
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Copper-catalyzed aerobic intramolecular carbo- and amino-oxygenation of alkynes for synthesis of azaheterocycles
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Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
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Copper-catalyzed aerobic aliphatic C–H oxygenation directed by an amidine moiety
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Part I: Pd(II)-catalyzed ring-expansion of cyclic 2-azidoalcohols for synthesis of azaheterocycles. Part II: Cu(II)-catalyzed aerobic oxidation of benzyl cyanides for synthesis of carboxylic acids
gan: Xu, Yanjun
Cyhoeddwyd: (2012)

Palladium-catalyzed regiocontrollable reductive Heck reaction of unactivated aliphatic alkenes
gan: Wang, Chengdong, et al.
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Radical-mediated diamination of alkenes with phenylhydrazine and azodicarboxylates : highly diastereoselective synthesis of trans-diamines from cycloalkenes
gan: Zhu, Ming-Kui, et al.
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Copper-catalyzed aliphatic C-H oxidation with Amidines and Amidoximes
gan: Chen, Hui
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Enantio- and Regioselective CuH-Catalyzed Hydroamination of Alkenes
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Cu–Rh redox relay catalysts for synthesis of azaheterocycles via C–H functionalization
gan: Chiba, Shunsuke
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Detailed mechanistic studies on palladium catalyzed selective C-H olefination with aliphatic alkenes: a significant influence of proton shuttling
gan: Deb, A, et al.
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Diastereo- and Enantioselective CuH-Catalyzed Hydroamination of Strained Trisubstituted Alkenes
gan: Feng, Sheng, et al.
Cyhoeddwyd: (2021)

P III /P V =O Catalyzed Cascade Synthesis of N‐Functionalized Azaheterocycles
gan: Nykaza, Trevor V, et al.
Cyhoeddwyd: (2021)

Studies of transition metal-mediated functionalization of alkynes for synthesis of azaheterocycles
gan: Too, Pei Chui
Cyhoeddwyd: (2014)

Enantioselective CuH-Catalyzed Anti-Markovnikov Hydroamination of 1,1-Disubstituted Alkenes
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Enantioselective CuH-Catalyzed Reductive Coupling of Aryl Alkenes and Activated Carboxylic Acids
gan: Bandar, Jeffrey, et al.
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Copper-mediated oxidative molecular transformations of N-alkenyl/alkynyl enamine carboxylates for synthesis of azaheterocycles
gan: Toh, Kah Kah
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Intermolecular reductive heck reaction of unactivated aliphatic alkenes with organohalides
gan: Zheng, Kewang, et al.
Cyhoeddwyd: (2022)

Palladium-Catalyzed Hydrophosphonylation of Alkenes with Dialkyl H-Phosphonates
gan: Candy, M, et al.
Cyhoeddwyd: (2014)

Development of synthetic methods of Azaheterocycles via Vinylic substitutions and an aerobic oxidation of allylic alcohols catalysed by N-Hydroxyindoles
gan: Shen, Shusu
Cyhoeddwyd: (2013)

Silyl radical-mediated activation of sulfamoyl chlorides enables direct access to aliphatic sulfonamides from alkenes
gan: Hell, SM, et al.
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Asymmetric Synthesis of Dialkyl Carbinols by Ni‐Catalyzed Reductive‐Oxidative Relay of Distinct Alkenes
gan: Quan‐Xing Zi, et al.
Cyhoeddwyd: (2024-12-01)

Diastereoselective aminooxygenation and diamination of alkenes with amidines by hypervalent iodine(III) reagents
gan: Chen, Hui, et al.
Cyhoeddwyd: (2015)

Diamine ligands in copper-catalyzed reactions
gan: Surry, David S., et al.
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Aerobic microorganism for the degradation of chlorinated aliphatic hydrocarbons /
gan: 320306 Fliermans, Carl B.

Sensitive and Discriminative Fluorescent Detection of Volatile Primary Aliphatic Diamine Vapors from Monoamines
gan: Agostino Attinà, et al.
Cyhoeddwyd: (2024-12-01)

Mn(iii)-catalyzed radical reactions of 1,3-dicarbonyl compounds and cyclopropanols with vinyl azides for divergent synthesis of azaheterocycles
gan: Chiba, Shunsuke
Cyhoeddwyd: (2015)

Electrophotochemical metal-catalyzed synthesis of alkylnitriles from simple aliphatic carboxylic acids
gan: Yukang Wang, et al.
Cyhoeddwyd: (2024-07-01)

Palladium-catalyzed remote internal C(sp 3)−H bond chlorination of alkenes
gan: Yao-Xin Wang, et al.
Cyhoeddwyd: (2024-12-01)

Copper-catalyzed enantioselective hydroamination of alkenes
gan: Liu, Richard, et al.
Cyhoeddwyd: (2020)

Copper-Catalyzed Oxytrifluoromethylation of Unactivated Alkenes
gan: Zhu, Rong, et al.
Cyhoeddwyd: (2015)

Part I : Synthesis of azaheterocycles from aryl ketone o-acetyl oximes and internal alkynes by Cu-Rh bimetallic relay catalysts. Part II: Synthesis of 3,4-2h-dihydropyrroles starting from alkenyl carbonitriles and grignard reagents via cu(ii)-mediated iminooxygenation of N-H imines with tempo.
gan: Chua, Sze Hui
Cyhoeddwyd: (2013)

Part I: synthesis of azaheterocycles from aryl ketone O-acetyl oximes and internal alkynes by Cu-Rh bimetallic relay catalysts. Part II: Synthesis of 3,4-2H-dihydropyrroles starting from alkenyl carbonitriles and grignard reagents via Cu(II)-mediated iminooxygenation of N-H imines with tempo
gan: Chua, Sze Hui
Cyhoeddwyd: (2013)

Transition metal-free amino-cyclization for the synthesis of saturated azaheterocycles
gan: Kaga, Atsushi
Cyhoeddwyd: (2018)

Iridium-catalyzed carbonyl group-directed oxidative coupling of arenes with alkenes
gan: Elumalai, Kumaran, et al.
Cyhoeddwyd: (2020)

Regio- and Enantioselective Synthesis of 1,2-Diamine Derivatives by Copper-Catalyzed Hydroamination
gan: Ichikawa, Saki, et al.
Cyhoeddwyd: (2020)

Anti-Markovnikov hydroallylation reaction of alkenes via scandium-catalyzed allylic C‒H activation
gan: Shiyu Wang, et al.
Cyhoeddwyd: (2025-02-01)

Manganese(III)-mediated reactions of vinyl azides and 1,3-dicarbonyl compounds or cyclopropanols : synthesis of azaheterocycles
gan: Wang, Yifeng
Cyhoeddwyd: (2011)

Studies on aminofunctionalization of carbon-carbon double bonds towards synthesis of azaheterocycles
gan: Stephen Sanjaya
Cyhoeddwyd: (2014)