Design, syntheses and applications of chiral transition metal complexes bearing phosphorus-containing ligands
A series of optically active tertiary phosphine compounds were prepared via catalytic asymmetric hydrophosphination of specially designed substrates. The C-stereogenic phosphines obtained were used in the formation of symmetrical PC(aryl)P, unsymmetrical PC(aryl)N and NC(sp3)X (X = O, S) transition...
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Format: | Thesis |
Language: | English |
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2015
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Online Access: | https://hdl.handle.net/10356/65840 |