Development of ligand functionalized fiber optic sensor for nickel ion detection

The elevated levels of heavy metal contaminants in the environment as a result of anthropogenic based activities pose a significant threat to human health. This has prompted an urgent need for the development of a simple, fast and cost-effective sensing technique for the detection of heavy metal ion...

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Main Author: Datar, Kritika
Other Authors: Chan Chi Chiu
Format: Final Year Project (FYP)
Language:English
Published: 2016
Subjects:
Online Access:http://hdl.handle.net/10356/68398
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author Datar, Kritika
author2 Chan Chi Chiu
author_facet Chan Chi Chiu
Datar, Kritika
author_sort Datar, Kritika
collection NTU
description The elevated levels of heavy metal contaminants in the environment as a result of anthropogenic based activities pose a significant threat to human health. This has prompted an urgent need for the development of a simple, fast and cost-effective sensing technique for the detection of heavy metal ions in the environment. In this study, a novel ligand functionalized fiber optic sensor consisting of a Single Mode Fiber (SMF) and a No Core Fiber (NCF) is proposed and demonstrated for Nickel ion detection. In order to evaluate the sensitivity of the fabricated sensor, a refractive index test was conducted. From the results obtained, it was observed that the interference dips shifted towards longer wavelengths as the RI of the surrounding medium was increased thus indicating that the sensor was sensitive to changes in RI. The surface of the sensor was then functionalized by the ligand Meso-Tetra (4- carboxyphenyl) porphine via the silane-coupling agent Triethoxysilane to allow the Ni2+ ions to be captured onto the surface of the sensor by the ligand receptors. Upon subjecting the functionalized sensor to different nickel ion concentrations, the interference dips in the reflectance spectrum observed to shift towards longer wavelengths with increasing nickel ion concentration. The sensitivity of the sensor was observed to be 121.03 nm/mM with R2 value = 0.8411 in the nickel concentration range up to 0.02mM, thereby providing evidence that the functionalized sensor demonstrated good sensitivity to nickel ions and therefore is a suitable alternative method for detecting the heavy metal nickel in water.
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spelling ntu-10356/683982023-03-03T15:36:38Z Development of ligand functionalized fiber optic sensor for nickel ion detection Datar, Kritika Chan Chi Chiu School of Chemical and Biomedical Engineering DRNTU::Engineering The elevated levels of heavy metal contaminants in the environment as a result of anthropogenic based activities pose a significant threat to human health. This has prompted an urgent need for the development of a simple, fast and cost-effective sensing technique for the detection of heavy metal ions in the environment. In this study, a novel ligand functionalized fiber optic sensor consisting of a Single Mode Fiber (SMF) and a No Core Fiber (NCF) is proposed and demonstrated for Nickel ion detection. In order to evaluate the sensitivity of the fabricated sensor, a refractive index test was conducted. From the results obtained, it was observed that the interference dips shifted towards longer wavelengths as the RI of the surrounding medium was increased thus indicating that the sensor was sensitive to changes in RI. The surface of the sensor was then functionalized by the ligand Meso-Tetra (4- carboxyphenyl) porphine via the silane-coupling agent Triethoxysilane to allow the Ni2+ ions to be captured onto the surface of the sensor by the ligand receptors. Upon subjecting the functionalized sensor to different nickel ion concentrations, the interference dips in the reflectance spectrum observed to shift towards longer wavelengths with increasing nickel ion concentration. The sensitivity of the sensor was observed to be 121.03 nm/mM with R2 value = 0.8411 in the nickel concentration range up to 0.02mM, thereby providing evidence that the functionalized sensor demonstrated good sensitivity to nickel ions and therefore is a suitable alternative method for detecting the heavy metal nickel in water. Bachelor of Engineering (Chemical and Biomolecular Engineering) 2016-05-25T08:58:22Z 2016-05-25T08:58:22Z 2016 Final Year Project (FYP) http://hdl.handle.net/10356/68398 en Nanyang Technological University 62 p. application/pdf
spellingShingle DRNTU::Engineering
Datar, Kritika
Development of ligand functionalized fiber optic sensor for nickel ion detection
title Development of ligand functionalized fiber optic sensor for nickel ion detection
title_full Development of ligand functionalized fiber optic sensor for nickel ion detection
title_fullStr Development of ligand functionalized fiber optic sensor for nickel ion detection
title_full_unstemmed Development of ligand functionalized fiber optic sensor for nickel ion detection
title_short Development of ligand functionalized fiber optic sensor for nickel ion detection
title_sort development of ligand functionalized fiber optic sensor for nickel ion detection
topic DRNTU::Engineering
url http://hdl.handle.net/10356/68398
work_keys_str_mv AT datarkritika developmentofligandfunctionalizedfiberopticsensorfornickeliondetection