Heavier Ester analogues : synthesis of amidinate-stabilized aryloxo silanechalcogenones
The first amidinate-stabilized aryloxosilylene [LSi(OAr)] (II, L = PhC(NtBu)2, Ar = 2,6-tBu2-4-MeC6H2) was synthesized by the reaction of the amidinate-stabilized chlorosilylene I with lithium 2,6-di-tert-butyl-4-methylphenyloxide in E120. After that, the amidinate-stabilized aryloxosilylene-bor...
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| Format: | Thesis |
| Language: | English |
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2016
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| Online Access: | http://hdl.handle.net/10356/68883 |