High temperature lead free solder

Due to its availability and affordability, Zinc-Aluminium (Zn-Al) based alloys have been studied extensively as a possible alternative for lead based solders. Furthermore, amongst the Zn based systems, Zn-Al possesses good thermal and mechanical properties. At present, plenty of studies have been do...

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Main Author: Song, Glenn Qi Xuan
Other Authors: Li King Ho Holden
Format: Final Year Project (FYP)
Language:English
Published: 2017
Subjects:
Online Access:http://hdl.handle.net/10356/71587
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author Song, Glenn Qi Xuan
author2 Li King Ho Holden
author_facet Li King Ho Holden
Song, Glenn Qi Xuan
author_sort Song, Glenn Qi Xuan
collection NTU
description Due to its availability and affordability, Zinc-Aluminium (Zn-Al) based alloys have been studied extensively as a possible alternative for lead based solders. Furthermore, amongst the Zn based systems, Zn-Al possesses good thermal and mechanical properties. At present, plenty of studies have been done mainly on the interconnecting properties and process optimization for solder reflow. In this study, we will explore how the addition of different elements such as Magnesium (Mg) and Germanium (Ge) will affect the thermo-mechanical properties. Furthermore, the effects of phase transformation on the properties will be studied as well. Four different Zn-Al alloys – Zn-6Al (ZA), ZN-4.3Al-4.2Mg (ZAM), Zn-8.4Al-8.4Ge (ZAG) and Zn-6.5Al-0.8Mg-1.0Ge (ZAMG) are prepared in an induction furnace under an inert Ar gas atmosphere and cast into cylindrical rod. Microstructures, thermal properties, thermal expansion, electrical resistivity and thermal conductivity measurements are analysed and compared. It is found that the addition of Mg or Ge will decrease the eutectic melting point. As for the coefficient of thermal expansion (CTE), Scanning Electron Microscopy (SEM) and X-ray Fluorescence (XRF) analyses have revealed that Zinc rich hexagonal closed packed (hcp) phase is responsible for the CTE differences. Increasing amount of Al content and decreasing amount of Mg or Ge content would result in the decrease inelectrical resistivity and an increase in thermal conductivity.
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spelling ntu-10356/715872023-03-04T19:05:01Z High temperature lead free solder Song, Glenn Qi Xuan Li King Ho Holden School of Mechanical and Aerospace Engineering DRNTU::Engineering::Mechanical engineering Due to its availability and affordability, Zinc-Aluminium (Zn-Al) based alloys have been studied extensively as a possible alternative for lead based solders. Furthermore, amongst the Zn based systems, Zn-Al possesses good thermal and mechanical properties. At present, plenty of studies have been done mainly on the interconnecting properties and process optimization for solder reflow. In this study, we will explore how the addition of different elements such as Magnesium (Mg) and Germanium (Ge) will affect the thermo-mechanical properties. Furthermore, the effects of phase transformation on the properties will be studied as well. Four different Zn-Al alloys – Zn-6Al (ZA), ZN-4.3Al-4.2Mg (ZAM), Zn-8.4Al-8.4Ge (ZAG) and Zn-6.5Al-0.8Mg-1.0Ge (ZAMG) are prepared in an induction furnace under an inert Ar gas atmosphere and cast into cylindrical rod. Microstructures, thermal properties, thermal expansion, electrical resistivity and thermal conductivity measurements are analysed and compared. It is found that the addition of Mg or Ge will decrease the eutectic melting point. As for the coefficient of thermal expansion (CTE), Scanning Electron Microscopy (SEM) and X-ray Fluorescence (XRF) analyses have revealed that Zinc rich hexagonal closed packed (hcp) phase is responsible for the CTE differences. Increasing amount of Al content and decreasing amount of Mg or Ge content would result in the decrease inelectrical resistivity and an increase in thermal conductivity. Bachelor of Engineering (Mechanical Engineering) 2017-05-17T08:55:50Z 2017-05-17T08:55:50Z 2017 Final Year Project (FYP) http://hdl.handle.net/10356/71587 en Nanyang Technological University 69 p. application/pdf
spellingShingle DRNTU::Engineering::Mechanical engineering
Song, Glenn Qi Xuan
High temperature lead free solder
title High temperature lead free solder
title_full High temperature lead free solder
title_fullStr High temperature lead free solder
title_full_unstemmed High temperature lead free solder
title_short High temperature lead free solder
title_sort high temperature lead free solder
topic DRNTU::Engineering::Mechanical engineering
url http://hdl.handle.net/10356/71587
work_keys_str_mv AT songglennqixuan hightemperatureleadfreesolder