Synthesis and optimisation of nickel : iron for electrocatalytic evolution

Owing to the abundance of Iron (Fe) and Nickel (Ni) in the Earth's crust and the relative good Oxygen Evolution Reaction (OER) electrocatalytic activity of NiO_x and FeO_x, the search for an optimal Ni : Fe-based catalyst as OER electrocat- alyst has become the motivation of this project....

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Main Author: Low, Cally Qian Ji
Other Authors: Fan Hongjin
Format: Final Year Project (FYP)
Language:English
Published: 2018
Subjects:
Online Access:http://hdl.handle.net/10356/74112
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author Low, Cally Qian Ji
author2 Fan Hongjin
author_facet Fan Hongjin
Low, Cally Qian Ji
author_sort Low, Cally Qian Ji
collection NTU
description Owing to the abundance of Iron (Fe) and Nickel (Ni) in the Earth's crust and the relative good Oxygen Evolution Reaction (OER) electrocatalytic activity of NiO_x and FeO_x, the search for an optimal Ni : Fe-based catalyst as OER electrocat- alyst has become the motivation of this project. By varying the molar ratios of metal and viscosity of the Ni : Fe precursors, the dip-coated Ni : Fe carbon cloth was annealed at di erent temperatures. This study achieved an optimised Ni : Fe electrocatalyst with superior OE electrocatalytic activities as a non noble metal catalyst. The fabricated Ni80% : Fe20% electrocatalyst annealed at 400 C, requires a low overpotential of 278:4 mV to achieve current density of 10 mA/cm^2 with a Tafel slope of 53.7 mV dec^-1. Moreover, the Ni80 % : Fe20% electrocatalyst exhibits stable chronopotentiometric behaviours over a duration of 20 hours under constant current density of 10 mA/cm^2 and 30 mA/cm^2.
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spelling ntu-10356/741122023-02-28T23:10:54Z Synthesis and optimisation of nickel : iron for electrocatalytic evolution Low, Cally Qian Ji Fan Hongjin School of Physical and Mathematical Sciences DRNTU::Science::Physics Owing to the abundance of Iron (Fe) and Nickel (Ni) in the Earth's crust and the relative good Oxygen Evolution Reaction (OER) electrocatalytic activity of NiO_x and FeO_x, the search for an optimal Ni : Fe-based catalyst as OER electrocat- alyst has become the motivation of this project. By varying the molar ratios of metal and viscosity of the Ni : Fe precursors, the dip-coated Ni : Fe carbon cloth was annealed at di erent temperatures. This study achieved an optimised Ni : Fe electrocatalyst with superior OE electrocatalytic activities as a non noble metal catalyst. The fabricated Ni80% : Fe20% electrocatalyst annealed at 400 C, requires a low overpotential of 278:4 mV to achieve current density of 10 mA/cm^2 with a Tafel slope of 53.7 mV dec^-1. Moreover, the Ni80 % : Fe20% electrocatalyst exhibits stable chronopotentiometric behaviours over a duration of 20 hours under constant current density of 10 mA/cm^2 and 30 mA/cm^2. Bachelor of Science in Physics 2018-04-26T01:32:36Z 2018-04-26T01:32:36Z 2018 Final Year Project (FYP) http://hdl.handle.net/10356/74112 en 67 p. application/pdf
spellingShingle DRNTU::Science::Physics
Low, Cally Qian Ji
Synthesis and optimisation of nickel : iron for electrocatalytic evolution
title Synthesis and optimisation of nickel : iron for electrocatalytic evolution
title_full Synthesis and optimisation of nickel : iron for electrocatalytic evolution
title_fullStr Synthesis and optimisation of nickel : iron for electrocatalytic evolution
title_full_unstemmed Synthesis and optimisation of nickel : iron for electrocatalytic evolution
title_short Synthesis and optimisation of nickel : iron for electrocatalytic evolution
title_sort synthesis and optimisation of nickel iron for electrocatalytic evolution
topic DRNTU::Science::Physics
url http://hdl.handle.net/10356/74112
work_keys_str_mv AT lowcallyqianji synthesisandoptimisationofnickelironforelectrocatalyticevolution