Improving efficiency of spinel structured catalyst for oxygen evolution reaction

With the ever-rising demand for energy and the effects of global warming intensifies, we turned to renewable energy as our source of energy. Hydrogen energy is one of them. Hydrogen can be harnessed through the water splitting process. However, the limiting factor of water splitting process is the l...

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書誌詳細
第一著者: Tan, Angeline Yan Jun
その他の著者: Xu Zhichuan Jason
フォーマット: Final Year Project (FYP)
言語:English
出版事項: 2019
主題:
オンライン・アクセス:http://hdl.handle.net/10356/76749
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author Tan, Angeline Yan Jun
author2 Xu Zhichuan Jason
author_facet Xu Zhichuan Jason
Tan, Angeline Yan Jun
author_sort Tan, Angeline Yan Jun
collection NTU
description With the ever-rising demand for energy and the effects of global warming intensifies, we turned to renewable energy as our source of energy. Hydrogen energy is one of them. Hydrogen can be harnessed through the water splitting process. However, the limiting factor of water splitting process is the lack of an efficient oxygen evolution reaction (OER) catalyst. Thus, many researches have been investigating the different types of metal oxides, in search of an efficient OER catalyst. In this report, spinel structured metal oxides such as Zn0.5Mn2.5O4, MgxMn3-xO4, MgxNi3-xO4 and MgxCo3-xO4 were synthesised by sol-gel technique to evaluate their OER performances in alkaline conditions. At overpotentials of 360 mV (1.59 V vs RHE) and 370 mV (1.60 V vs RHE), Mg0.25Co2.75O4 electrode and Mg0.5Co2.5O4 electrode respectively recorded the highest OER performances among the other spinel metal oxides in this report at a current density of 10 mA cm-2. With a Tafel slope of 52 mV dec-1 and 51 mV dec-1, Mg0.25Co2.75O4 and Mg0.5Co2.5O4 respectively exhibited high stability in 0.1 M KOH solution. The stable and highly OER performances of MgxCo3-xO4 has exhibited high potential to be used in water electrolysers in alkaline media.
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spelling ntu-10356/767492023-03-04T15:36:59Z Improving efficiency of spinel structured catalyst for oxygen evolution reaction Tan, Angeline Yan Jun Xu Zhichuan Jason School of Materials Science and Engineering DRNTU::Engineering::Materials With the ever-rising demand for energy and the effects of global warming intensifies, we turned to renewable energy as our source of energy. Hydrogen energy is one of them. Hydrogen can be harnessed through the water splitting process. However, the limiting factor of water splitting process is the lack of an efficient oxygen evolution reaction (OER) catalyst. Thus, many researches have been investigating the different types of metal oxides, in search of an efficient OER catalyst. In this report, spinel structured metal oxides such as Zn0.5Mn2.5O4, MgxMn3-xO4, MgxNi3-xO4 and MgxCo3-xO4 were synthesised by sol-gel technique to evaluate their OER performances in alkaline conditions. At overpotentials of 360 mV (1.59 V vs RHE) and 370 mV (1.60 V vs RHE), Mg0.25Co2.75O4 electrode and Mg0.5Co2.5O4 electrode respectively recorded the highest OER performances among the other spinel metal oxides in this report at a current density of 10 mA cm-2. With a Tafel slope of 52 mV dec-1 and 51 mV dec-1, Mg0.25Co2.75O4 and Mg0.5Co2.5O4 respectively exhibited high stability in 0.1 M KOH solution. The stable and highly OER performances of MgxCo3-xO4 has exhibited high potential to be used in water electrolysers in alkaline media. Bachelor of Engineering (Materials Engineering) 2019-04-08T13:35:47Z 2019-04-08T13:35:47Z 2019 Final Year Project (FYP) http://hdl.handle.net/10356/76749 en Nanyang Technological University 50 p. application/pdf
spellingShingle DRNTU::Engineering::Materials
Tan, Angeline Yan Jun
Improving efficiency of spinel structured catalyst for oxygen evolution reaction
title Improving efficiency of spinel structured catalyst for oxygen evolution reaction
title_full Improving efficiency of spinel structured catalyst for oxygen evolution reaction
title_fullStr Improving efficiency of spinel structured catalyst for oxygen evolution reaction
title_full_unstemmed Improving efficiency of spinel structured catalyst for oxygen evolution reaction
title_short Improving efficiency of spinel structured catalyst for oxygen evolution reaction
title_sort improving efficiency of spinel structured catalyst for oxygen evolution reaction
topic DRNTU::Engineering::Materials
url http://hdl.handle.net/10356/76749
work_keys_str_mv AT tanangelineyanjun improvingefficiencyofspinelstructuredcatalystforoxygenevolutionreaction