Enhancement of rate of nitrogen reduction reaction for ammonia synthesis using cobalt oxide electrocatalyst

Ammonia production is an essential for fertilization and nitrogen compounds, it can also be used as hydrogen energy carrier and alternative fuel for vehicles. The Haber-Bosch process is the main method used to produce ammonia currently, which is energy intensive and costly. The process also utilizes...

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Main Author: Aw, Yuh Meei
Other Authors: Alex Yan Qingyu
Format: Final Year Project (FYP)
Language:English
Published: 2019
Subjects:
Online Access:http://hdl.handle.net/10356/77442
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author Aw, Yuh Meei
author2 Alex Yan Qingyu
author_facet Alex Yan Qingyu
Aw, Yuh Meei
author_sort Aw, Yuh Meei
collection NTU
description Ammonia production is an essential for fertilization and nitrogen compounds, it can also be used as hydrogen energy carrier and alternative fuel for vehicles. The Haber-Bosch process is the main method used to produce ammonia currently, which is energy intensive and costly. The process also utilizes a large amount of fossil fuels and emits carbon dioxide, contributing to environmental pollution. Therefore, it is critical to find a sustainable and environmentally friendly solution for ammonia synthesis. The use of nano-catalysts in an electrochemical system under ambient conditions is considered as an alternative for the synthesis of ammonia. In this paper, we will report the performance of Co3O4 nanorods as catalysts to enhance the nitrogen reduction reaction for ammonia synthesis. The nanorods are synthesized by hydrothermal synthesis of the cobalt oxide mixture. The samples will be characterized via Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD,) Cyclic Voltammetry (CV), Linear Sweep Voltammetry (LSV), Electrochemical Open Circuit Voltage (OCV), chrono-amperometry, faradaic efficiency and electrochemical impedance testing. After the characterization tests, the SEM and XRD results obtained illustrated that Co3O4 nanorods were formed as a result of hydrothermal synthesis. This work will provide an opportunity to improve the yield of ammonia via electrochemical synthesis and will be a definitely aid in reducing environmental pollution.
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spelling ntu-10356/774422023-03-04T15:39:41Z Enhancement of rate of nitrogen reduction reaction for ammonia synthesis using cobalt oxide electrocatalyst Aw, Yuh Meei Alex Yan Qingyu School of Materials Science and Engineering DRNTU::Engineering::Materials Ammonia production is an essential for fertilization and nitrogen compounds, it can also be used as hydrogen energy carrier and alternative fuel for vehicles. The Haber-Bosch process is the main method used to produce ammonia currently, which is energy intensive and costly. The process also utilizes a large amount of fossil fuels and emits carbon dioxide, contributing to environmental pollution. Therefore, it is critical to find a sustainable and environmentally friendly solution for ammonia synthesis. The use of nano-catalysts in an electrochemical system under ambient conditions is considered as an alternative for the synthesis of ammonia. In this paper, we will report the performance of Co3O4 nanorods as catalysts to enhance the nitrogen reduction reaction for ammonia synthesis. The nanorods are synthesized by hydrothermal synthesis of the cobalt oxide mixture. The samples will be characterized via Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD,) Cyclic Voltammetry (CV), Linear Sweep Voltammetry (LSV), Electrochemical Open Circuit Voltage (OCV), chrono-amperometry, faradaic efficiency and electrochemical impedance testing. After the characterization tests, the SEM and XRD results obtained illustrated that Co3O4 nanorods were formed as a result of hydrothermal synthesis. This work will provide an opportunity to improve the yield of ammonia via electrochemical synthesis and will be a definitely aid in reducing environmental pollution. Bachelor of Engineering (Materials Engineering) 2019-05-29T03:32:24Z 2019-05-29T03:32:24Z 2019 Final Year Project (FYP) http://hdl.handle.net/10356/77442 en Nanyang Technological University 34 p. application/pdf
spellingShingle DRNTU::Engineering::Materials
Aw, Yuh Meei
Enhancement of rate of nitrogen reduction reaction for ammonia synthesis using cobalt oxide electrocatalyst
title Enhancement of rate of nitrogen reduction reaction for ammonia synthesis using cobalt oxide electrocatalyst
title_full Enhancement of rate of nitrogen reduction reaction for ammonia synthesis using cobalt oxide electrocatalyst
title_fullStr Enhancement of rate of nitrogen reduction reaction for ammonia synthesis using cobalt oxide electrocatalyst
title_full_unstemmed Enhancement of rate of nitrogen reduction reaction for ammonia synthesis using cobalt oxide electrocatalyst
title_short Enhancement of rate of nitrogen reduction reaction for ammonia synthesis using cobalt oxide electrocatalyst
title_sort enhancement of rate of nitrogen reduction reaction for ammonia synthesis using cobalt oxide electrocatalyst
topic DRNTU::Engineering::Materials
url http://hdl.handle.net/10356/77442
work_keys_str_mv AT awyuhmeei enhancementofrateofnitrogenreductionreactionforammoniasynthesisusingcobaltoxideelectrocatalyst