High efficiency solid-state sensitized solar cell-based on submicrometer rutile TiO2 nanorod and CH3NH3PbI3 perovskite sensitizer
We report a highly efficient solar cell based on a submicrometer (0.6 μm) rutile TiO2 nanorod sensitized with CH3NH3PbI3 perovskite nanodots. Rutile nanorods were grown hydrothermally and their lengths were varied through the control of the reaction time. Infiltration of spiro-MeOTAD hole transport...
| Principais autores: | , , , , , , , |
|---|---|
| Outros Autores: | |
| Formato: | Journal Article |
| Idioma: | English |
| Publicado em: |
2013
|
| Assuntos: | |
| Acesso em linha: | https://hdl.handle.net/10356/79528 http://hdl.handle.net/10220/17878 |
| _version_ | 1826129417242411008 |
|---|---|
| author | Kulkarni, Sneha A. Boix, Pablo P. Kim, Hui-Seon Lee, Jin-Wook Yantara, Natalia Mhaisalkar, Subodh Gautam Grätzel, Michael Park, Nam-Gyu |
| author2 | Energy Research Institute @ NTU (ERI@N) |
| author_facet | Energy Research Institute @ NTU (ERI@N) Kulkarni, Sneha A. Boix, Pablo P. Kim, Hui-Seon Lee, Jin-Wook Yantara, Natalia Mhaisalkar, Subodh Gautam Grätzel, Michael Park, Nam-Gyu |
| author_sort | Kulkarni, Sneha A. |
| collection | NTU |
| description | We report a highly efficient solar cell based on a submicrometer (0.6 μm) rutile TiO2 nanorod sensitized with CH3NH3PbI3 perovskite nanodots. Rutile nanorods were grown hydrothermally and their lengths were varied through the control of the reaction time. Infiltration of spiro-MeOTAD hole transport material into the perovskite-sensitized nanorod films demonstrated photocurrent density of 15.6 mA/cm2, voltage of 955 mV, and fill factor of 0.63, leading to a power conversion efficiency (PCE) of 9.4% under the simulated AM 1.5G one sun illumination. Photovoltaic performance was significantly dependent on the length of the nanorods, where both photocurrent and voltage decreased with increasing nanorod lengths. A continuous drop of voltage with increasing nanorod length correlated with charge generation efficiency rather than recombination kinetics with impedance spectroscopic characterization displaying similar recombination regardless of the nanorod length. |
| first_indexed | 2024-10-01T07:40:15Z |
| format | Journal Article |
| id | ntu-10356/79528 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T07:40:15Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/795282021-01-08T07:50:53Z High efficiency solid-state sensitized solar cell-based on submicrometer rutile TiO2 nanorod and CH3NH3PbI3 perovskite sensitizer Kulkarni, Sneha A. Boix, Pablo P. Kim, Hui-Seon Lee, Jin-Wook Yantara, Natalia Mhaisalkar, Subodh Gautam Grätzel, Michael Park, Nam-Gyu Energy Research Institute @ NTU (ERI@N) Nano letters We report a highly efficient solar cell based on a submicrometer (0.6 μm) rutile TiO2 nanorod sensitized with CH3NH3PbI3 perovskite nanodots. Rutile nanorods were grown hydrothermally and their lengths were varied through the control of the reaction time. Infiltration of spiro-MeOTAD hole transport material into the perovskite-sensitized nanorod films demonstrated photocurrent density of 15.6 mA/cm2, voltage of 955 mV, and fill factor of 0.63, leading to a power conversion efficiency (PCE) of 9.4% under the simulated AM 1.5G one sun illumination. Photovoltaic performance was significantly dependent on the length of the nanorods, where both photocurrent and voltage decreased with increasing nanorod lengths. A continuous drop of voltage with increasing nanorod length correlated with charge generation efficiency rather than recombination kinetics with impedance spectroscopic characterization displaying similar recombination regardless of the nanorod length. Accepted version 2013-11-27T06:07:27Z 2019-12-06T13:27:30Z 2013-11-27T06:07:27Z 2019-12-06T13:27:30Z 2013 2013 Journal Article Kim, H. S., Lee, J. W., Yantara, N., Boix, P. P., Kulkarni, S. A., Mhaisalkar, S., Grätzel, M.,& Park, N. G. (2013). High Efficiency Solid-State Sensitized Solar Cell-Based on Submicrometer Rutile TiO2 Nanorod and CH3NH3PbI3 Perovskite Sensitizer. Nano Letters, 13(6), 2412-2417. https://hdl.handle.net/10356/79528 http://hdl.handle.net/10220/17878 10.1021/nl400286w en Nano letters © 2013 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Nano Letter, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: http://dx.doi.org/10.1021/nl400286w. 36 p. application/pdf |
| spellingShingle | Nano letters Kulkarni, Sneha A. Boix, Pablo P. Kim, Hui-Seon Lee, Jin-Wook Yantara, Natalia Mhaisalkar, Subodh Gautam Grätzel, Michael Park, Nam-Gyu High efficiency solid-state sensitized solar cell-based on submicrometer rutile TiO2 nanorod and CH3NH3PbI3 perovskite sensitizer |
| title | High efficiency solid-state sensitized solar cell-based on submicrometer rutile TiO2 nanorod and CH3NH3PbI3 perovskite sensitizer |
| title_full | High efficiency solid-state sensitized solar cell-based on submicrometer rutile TiO2 nanorod and CH3NH3PbI3 perovskite sensitizer |
| title_fullStr | High efficiency solid-state sensitized solar cell-based on submicrometer rutile TiO2 nanorod and CH3NH3PbI3 perovskite sensitizer |
| title_full_unstemmed | High efficiency solid-state sensitized solar cell-based on submicrometer rutile TiO2 nanorod and CH3NH3PbI3 perovskite sensitizer |
| title_short | High efficiency solid-state sensitized solar cell-based on submicrometer rutile TiO2 nanorod and CH3NH3PbI3 perovskite sensitizer |
| title_sort | high efficiency solid state sensitized solar cell based on submicrometer rutile tio2 nanorod and ch3nh3pbi3 perovskite sensitizer |
| topic | Nano letters |
| url | https://hdl.handle.net/10356/79528 http://hdl.handle.net/10220/17878 |
| work_keys_str_mv | AT kulkarnisnehaa highefficiencysolidstatesensitizedsolarcellbasedonsubmicrometerrutiletio2nanorodandch3nh3pbi3perovskitesensitizer AT boixpablop highefficiencysolidstatesensitizedsolarcellbasedonsubmicrometerrutiletio2nanorodandch3nh3pbi3perovskitesensitizer AT kimhuiseon highefficiencysolidstatesensitizedsolarcellbasedonsubmicrometerrutiletio2nanorodandch3nh3pbi3perovskitesensitizer AT leejinwook highefficiencysolidstatesensitizedsolarcellbasedonsubmicrometerrutiletio2nanorodandch3nh3pbi3perovskitesensitizer AT yantaranatalia highefficiencysolidstatesensitizedsolarcellbasedonsubmicrometerrutiletio2nanorodandch3nh3pbi3perovskitesensitizer AT mhaisalkarsubodhgautam highefficiencysolidstatesensitizedsolarcellbasedonsubmicrometerrutiletio2nanorodandch3nh3pbi3perovskitesensitizer AT gratzelmichael highefficiencysolidstatesensitizedsolarcellbasedonsubmicrometerrutiletio2nanorodandch3nh3pbi3perovskitesensitizer AT parknamgyu highefficiencysolidstatesensitizedsolarcellbasedonsubmicrometerrutiletio2nanorodandch3nh3pbi3perovskitesensitizer |