Formal hydration of non-activated terminal olefins using tandem catalysts
The hydration of terminal olefins to secondary alcohols has been achieved using a Pd(II)/Ru(II) catalyst combination with high regioselectivity and yields. Both vinyl arenes and aliphatic olefins can be hydrated easily with the tandem catalyst system using a low catalyst loading of 1 mol%.
| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2016
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/81016 http://hdl.handle.net/10220/40662 |
| _version_ | 1811691695551545344 |
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| author | Yang, Yongsheng Guo, Jiayi Ng, Huimin Chen, Zhiyong Teo, Peili |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Yang, Yongsheng Guo, Jiayi Ng, Huimin Chen, Zhiyong Teo, Peili |
| author_sort | Yang, Yongsheng |
| collection | NTU |
| description | The hydration of terminal olefins to secondary alcohols has been achieved using a Pd(II)/Ru(II) catalyst combination with high regioselectivity and yields. Both vinyl arenes and aliphatic olefins can be hydrated easily with the tandem catalyst system using a low catalyst loading of 1 mol%. |
| first_indexed | 2024-10-01T06:23:59Z |
| format | Journal Article |
| id | ntu-10356/81016 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T06:23:59Z |
| publishDate | 2016 |
| record_format | dspace |
| spelling | ntu-10356/810162023-07-14T15:44:41Z Formal hydration of non-activated terminal olefins using tandem catalysts Yang, Yongsheng Guo, Jiayi Ng, Huimin Chen, Zhiyong Teo, Peili School of Materials Science & Engineering Secondary alcohols The hydration of terminal olefins to secondary alcohols has been achieved using a Pd(II)/Ru(II) catalyst combination with high regioselectivity and yields. Both vinyl arenes and aliphatic olefins can be hydrated easily with the tandem catalyst system using a low catalyst loading of 1 mol%. ASTAR (Agency for Sci., Tech. and Research, S’pore) Accepted version 2016-06-13T04:06:27Z 2019-12-06T14:19:38Z 2016-06-13T04:06:27Z 2019-12-06T14:19:38Z 2014 2014 Journal Article Yang, Y., Guo, J., Ng, H., Chen, Z., & Teo, P. (2014). Formal hydration of non-activated terminal olefins using tandem catalysts. Chemical Communications, 50(20), 2608-2611. 1359-7345 https://hdl.handle.net/10356/81016 http://hdl.handle.net/10220/40662 10.1039/c3cc48810a 194405 en Chemical Communications © 2014 The Royal Society of Chemistry. This is the author created version of a work that has been peer reviewed and accepted for publication by Chemical Communications, The Royal Society of Chemistry. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/ 10.1039/c3cc48810a]. application/pdf |
| spellingShingle | Secondary alcohols Yang, Yongsheng Guo, Jiayi Ng, Huimin Chen, Zhiyong Teo, Peili Formal hydration of non-activated terminal olefins using tandem catalysts |
| title | Formal hydration of non-activated terminal olefins using tandem catalysts |
| title_full | Formal hydration of non-activated terminal olefins using tandem catalysts |
| title_fullStr | Formal hydration of non-activated terminal olefins using tandem catalysts |
| title_full_unstemmed | Formal hydration of non-activated terminal olefins using tandem catalysts |
| title_short | Formal hydration of non-activated terminal olefins using tandem catalysts |
| title_sort | formal hydration of non activated terminal olefins using tandem catalysts |
| topic | Secondary alcohols |
| url | https://hdl.handle.net/10356/81016 http://hdl.handle.net/10220/40662 |
| work_keys_str_mv | AT yangyongsheng formalhydrationofnonactivatedterminalolefinsusingtandemcatalysts AT guojiayi formalhydrationofnonactivatedterminalolefinsusingtandemcatalysts AT nghuimin formalhydrationofnonactivatedterminalolefinsusingtandemcatalysts AT chenzhiyong formalhydrationofnonactivatedterminalolefinsusingtandemcatalysts AT teopeili formalhydrationofnonactivatedterminalolefinsusingtandemcatalysts |