A New 3D Metal–organic Frameworks with Tetranuclear Cadmium(II) Clusters: Synthesis, Structure, and Luminescent Property
A unique metal-organic framework [Cd2(L)1.5(μ3-OH)(H2O)2]·2H2O(1, H2L = 2,5-dibenzoylterephthalic acid) has been synthesized under hydrothermal conditions, and characterized by single-crystal X-ray diffractions, elemental analyses, IR spectra and fluorescence spectrum. The compound is of triclinic s...
| Main Authors: | , , , , , , , , , |
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| Format: | Journal Article |
| Language: | English |
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2016
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| Online Access: | https://hdl.handle.net/10356/81915 http://hdl.handle.net/10220/39710 http://manu30.magtech.com.cn/jghx/EN/ |
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| author | Zhu, Xiao-Fei Wang, Ning Xie, Xiao-Yan Hou, Rui-Bin Zhou, De-Feng Li, Ya-Feng Hu, Jun Li, Xin-Yuan Liu, He Nie, Wang |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Zhu, Xiao-Fei Wang, Ning Xie, Xiao-Yan Hou, Rui-Bin Zhou, De-Feng Li, Ya-Feng Hu, Jun Li, Xin-Yuan Liu, He Nie, Wang |
| author_sort | Zhu, Xiao-Fei |
| collection | NTU |
| description | A unique metal-organic framework [Cd2(L)1.5(μ3-OH)(H2O)2]·2H2O(1, H2L = 2,5-dibenzoylterephthalic acid) has been synthesized under hydrothermal conditions, and characterized by single-crystal X-ray diffractions, elemental analyses, IR spectra and fluorescence spectrum. The compound is of triclinic system, space group Pī, C33H27CdO14, Mr = 870.33, α = 12.2939(17), b = 12.5135(9), c = 13.2046(10) Å, α= 115.3190(10), β96.9140(10), γ = 109.7950(10)°, V = 1641.6(3) Å3, Z = 2, Dc = 1.761 g/cm3, F(000) = 862, μ(MoKa) = 1.366 mm-1, Rint = 0.0148, R = 0.0240 and wR = 0.0639 for 5995 observed reflections with I > 2σ(I). X-ray analysis shows that the title complex exhibits a 3D framework with (412·63) topology, in which the tetra-nuclear [Cd4(µ3-OH)2] clusters act as 6-connected nodes, and the L ligands can be simplified to be linear connectors. Moreover, the thermal stability and fluorescence have been studied in detail. |
| first_indexed | 2024-10-01T04:00:17Z |
| format | Journal Article |
| id | ntu-10356/81915 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T04:00:17Z |
| publishDate | 2016 |
| record_format | dspace |
| spelling | ntu-10356/819152023-07-14T15:50:15Z A New 3D Metal–organic Frameworks with Tetranuclear Cadmium(II) Clusters: Synthesis, Structure, and Luminescent Property Zhu, Xiao-Fei Wang, Ning Xie, Xiao-Yan Hou, Rui-Bin Zhou, De-Feng Li, Ya-Feng Hu, Jun Li, Xin-Yuan Liu, He Nie, Wang School of Materials Science & Engineering Hydrothermal Tetranuclear cluster Luminescence 2,5-dibenzoylterephthalic acid Crystal structure A unique metal-organic framework [Cd2(L)1.5(μ3-OH)(H2O)2]·2H2O(1, H2L = 2,5-dibenzoylterephthalic acid) has been synthesized under hydrothermal conditions, and characterized by single-crystal X-ray diffractions, elemental analyses, IR spectra and fluorescence spectrum. The compound is of triclinic system, space group Pī, C33H27CdO14, Mr = 870.33, α = 12.2939(17), b = 12.5135(9), c = 13.2046(10) Å, α= 115.3190(10), β96.9140(10), γ = 109.7950(10)°, V = 1641.6(3) Å3, Z = 2, Dc = 1.761 g/cm3, F(000) = 862, μ(MoKa) = 1.366 mm-1, Rint = 0.0148, R = 0.0240 and wR = 0.0639 for 5995 observed reflections with I > 2σ(I). X-ray analysis shows that the title complex exhibits a 3D framework with (412·63) topology, in which the tetra-nuclear [Cd4(µ3-OH)2] clusters act as 6-connected nodes, and the L ligands can be simplified to be linear connectors. Moreover, the thermal stability and fluorescence have been studied in detail. Published version 2016-01-19T07:05:45Z 2019-12-06T14:42:58Z 2016-01-19T07:05:45Z 2019-12-06T14:42:58Z 2013 Journal Article Zhu, X.-F., Wang, N., Xie, X.-Y., Hou, R.-B., Zhou, D.-F., Li, Y.-F., et al. (2013). A New 3D Metal–organic Frameworks with Tetranuclear Cadmium(II) Clusters: Synthesis, Structure, and Luminescent Property. Chinese Journal of Structural Chemistry, 33(2), 277-283. 0254-5861 https://hdl.handle.net/10356/81915 http://hdl.handle.net/10220/39710 http://manu30.magtech.com.cn/jghx/EN/ en Chinese Journal of Structural Chemistry © 2014 Editorial Board of Chinese Journal of Structural Chemistry. This paper was published in Chinese Journal of Structural Chemistry and is made available as an electronic reprint (preprint) with permission of Editorial Board of Chinese Journal of Structural Chemistry. The published version is available at: [http://manu30.magtech.com.cn/jghx/EN/]. One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper is prohibited and is subject to penalties under law. 7 p. application/pdf |
| spellingShingle | Hydrothermal Tetranuclear cluster Luminescence 2,5-dibenzoylterephthalic acid Crystal structure Zhu, Xiao-Fei Wang, Ning Xie, Xiao-Yan Hou, Rui-Bin Zhou, De-Feng Li, Ya-Feng Hu, Jun Li, Xin-Yuan Liu, He Nie, Wang A New 3D Metal–organic Frameworks with Tetranuclear Cadmium(II) Clusters: Synthesis, Structure, and Luminescent Property |
| title | A New 3D Metal–organic Frameworks with Tetranuclear Cadmium(II) Clusters: Synthesis, Structure, and Luminescent Property |
| title_full | A New 3D Metal–organic Frameworks with Tetranuclear Cadmium(II) Clusters: Synthesis, Structure, and Luminescent Property |
| title_fullStr | A New 3D Metal–organic Frameworks with Tetranuclear Cadmium(II) Clusters: Synthesis, Structure, and Luminescent Property |
| title_full_unstemmed | A New 3D Metal–organic Frameworks with Tetranuclear Cadmium(II) Clusters: Synthesis, Structure, and Luminescent Property |
| title_short | A New 3D Metal–organic Frameworks with Tetranuclear Cadmium(II) Clusters: Synthesis, Structure, and Luminescent Property |
| title_sort | new 3d metal organic frameworks with tetranuclear cadmium ii clusters synthesis structure and luminescent property |
| topic | Hydrothermal Tetranuclear cluster Luminescence 2,5-dibenzoylterephthalic acid Crystal structure |
| url | https://hdl.handle.net/10356/81915 http://hdl.handle.net/10220/39710 http://manu30.magtech.com.cn/jghx/EN/ |
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