Preparation, Structural Analysis, and Reactivity Studies of Phosphenium Dications
This work expands on the recent synthesis and reactivity of the two-coordinate P(III)-containing dication [((Ph3P)2C)P(NiPr2)]2+ (3a2+). Two additional dications of general formula [((RPh2P)2C)P(NR′2)]2+ (3b2+, R = 1/2 (CH2)3, R′ = iPr; 3c2+, R = Ph, R′ = Cy) have been prepared. Solution and solid-s...
Main Authors: | Tay, Madelyn Qin Yi, Ilić, Gordana, Werner-Zwanziger, Ulrike, Lu, Yunpeng, Ganguly, Rakesh, Ricard, Louis, Frison, Gilles, Carmichael, Duncan, Vidović, Dragoslav |
---|---|
Other Authors: | School of Physical and Mathematical Sciences |
Format: | Journal Article |
Language: | English |
Published: |
2016
|
Subjects: | |
Online Access: | https://hdl.handle.net/10356/81920 http://hdl.handle.net/10220/39724 |
Similar Items
-
C-F bond activation by transient phosphenium dications
by: Đorđević, Nemanja, et al.
Published: (2015) -
Oxidation of a P-C Bond under Mild Conditions
by: Ilić, Gordana, et al.
Published: (2016) -
Boron analogue of vinylidene dication supported by phosphines
by: Lu, Wei, et al.
Published: (2020) -
Applying Macromolecular Crowding to 3D Bioprinting: Fabrication of 3D Hierarchical Porous Collagen-based Hydrogel Constructs
by: Ng, Wei Long, et al.
Published: (2018) -
Phase-separating peptides for direct cytosolic delivery and redox-activated release of macromolecular therapeutics
by: Sun, Yue, et al.
Published: (2022)