1,2,4,3-Triazaborole-based neutral oxoborane stabilized by a Lewis acid

The first example of 1,2,4,3-triazaborole-based oxoborane has been synthesized via hydrogen migration upon the coordination of AlCl3 to the corresponding borinic acid. X-ray diffraction analysis and computational study disclosed the partial B[double bond, length as m-dash]O double-bond property.

Bibliographic Details
Main Authors: Loh, Ying Kai, Chong, Che Chang, Ganguly, Rakesh, Li, Yongxin, Vidovic, Dragoslav, Kinjo, Rei
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2016
Subjects:
Online Access:https://hdl.handle.net/10356/81976
http://hdl.handle.net/10220/41051
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author Loh, Ying Kai
Chong, Che Chang
Ganguly, Rakesh
Li, Yongxin
Vidovic, Dragoslav
Kinjo, Rei
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Loh, Ying Kai
Chong, Che Chang
Ganguly, Rakesh
Li, Yongxin
Vidovic, Dragoslav
Kinjo, Rei
author_sort Loh, Ying Kai
collection NTU
description The first example of 1,2,4,3-triazaborole-based oxoborane has been synthesized via hydrogen migration upon the coordination of AlCl3 to the corresponding borinic acid. X-ray diffraction analysis and computational study disclosed the partial B[double bond, length as m-dash]O double-bond property.
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spelling ntu-10356/819762020-03-07T12:31:29Z 1,2,4,3-Triazaborole-based neutral oxoborane stabilized by a Lewis acid Loh, Ying Kai Chong, Che Chang Ganguly, Rakesh Li, Yongxin Vidovic, Dragoslav Kinjo, Rei School of Physical and Mathematical Sciences borane derivative ab initio calculation The first example of 1,2,4,3-triazaborole-based oxoborane has been synthesized via hydrogen migration upon the coordination of AlCl3 to the corresponding borinic acid. X-ray diffraction analysis and computational study disclosed the partial B[double bond, length as m-dash]O double-bond property. ASTAR (Agency for Sci., Tech. and Research, S’pore) 2016-08-03T08:52:42Z 2019-12-06T14:44:04Z 2016-08-03T08:52:42Z 2019-12-06T14:44:04Z 2014 Journal Article Loh, Y. K., Chong, C. C., Ganguly, R., Li, Y., Vidovic, D., & Kinjo, R. (2014). 1,2,4,3-Triazaborole-based neutral oxoborane stabilized by a Lewis acid. Chemical Communications, 50(62), 8561-8564. https://hdl.handle.net/10356/81976 http://hdl.handle.net/10220/41051 10.1039/C4CC03379E en Chemical Communications © 2014 The Royal Society of Chemistry. 4 p.
spellingShingle borane derivative
ab initio calculation
Loh, Ying Kai
Chong, Che Chang
Ganguly, Rakesh
Li, Yongxin
Vidovic, Dragoslav
Kinjo, Rei
1,2,4,3-Triazaborole-based neutral oxoborane stabilized by a Lewis acid
title 1,2,4,3-Triazaborole-based neutral oxoborane stabilized by a Lewis acid
title_full 1,2,4,3-Triazaborole-based neutral oxoborane stabilized by a Lewis acid
title_fullStr 1,2,4,3-Triazaborole-based neutral oxoborane stabilized by a Lewis acid
title_full_unstemmed 1,2,4,3-Triazaborole-based neutral oxoborane stabilized by a Lewis acid
title_short 1,2,4,3-Triazaborole-based neutral oxoborane stabilized by a Lewis acid
title_sort 1 2 4 3 triazaborole based neutral oxoborane stabilized by a lewis acid
topic borane derivative
ab initio calculation
url https://hdl.handle.net/10356/81976
http://hdl.handle.net/10220/41051
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