Mid-infrared emissive InAsSb quantum dots grown by metal–organic chemical vapor deposition

InAsSb islands/quantum dots (QDs) emitting at wavelength >2.8 μm were self-assembled on InP substrate by using metal–organic chemical vapor deposition (MOCVD). Instead of using arsine, the safer organic tert-butylarsine (TBAs) was used as the arsenic source in the growth process. Effects of the g...

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Main Authors: Tang, Xiaohong, Zhang, Baolin, Yin, Zongyou
Other Authors: School of Electrical and Electronic Engineering
Format: Journal Article
Language:English
Published: 2016
Subjects:
Online Access:https://hdl.handle.net/10356/82076
http://hdl.handle.net/10220/39757
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author Tang, Xiaohong
Zhang, Baolin
Yin, Zongyou
author2 School of Electrical and Electronic Engineering
author_facet School of Electrical and Electronic Engineering
Tang, Xiaohong
Zhang, Baolin
Yin, Zongyou
author_sort Tang, Xiaohong
collection NTU
description InAsSb islands/quantum dots (QDs) emitting at wavelength >2.8 μm were self-assembled on InP substrate by using metal–organic chemical vapor deposition (MOCVD). Instead of using arsine, the safer organic tert-butylarsine (TBAs) was used as the arsenic source in the growth process. Effects of the growth conditions, i.e. substrate temperature and the growth rate, on the InAsSb QD formations have been studied. A narrow temperature window from 450 °C to 470 °C was found for growing high quality InAsSb QDs. InAsSb rings instead of islands/dots were formed using the conventional Stranski–Krastanow (S–K) growth mode if the growth rate was low or if InAsSb was grown for a longer time. By increasing the V : III ratio for the InAsSb growth, InAsSb islands/dots were formed with the same growth rate. To reduce the dot size and increase the InAsSb QD density, an alternative interruption growth (AIG) method was proposed and investigated. Using the AIG growth method, much higher dot density of the InAsSb QDs has been achieved, about 3 × 109 cm−2, which is about 10 times of that of the QDs grown by using the conventional S–K growth method. Strong photoluminescence emissions of the InAsSb islands/dots were observed. At room temperature, the emission wavelength of the InAsSb islands/dots was measured at >2.8 μm.
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spelling ntu-10356/820762020-03-07T13:57:22Z Mid-infrared emissive InAsSb quantum dots grown by metal–organic chemical vapor deposition Tang, Xiaohong Zhang, Baolin Yin, Zongyou School of Electrical and Electronic Engineering Quantum dots InAsSb islands/quantum dots (QDs) emitting at wavelength >2.8 μm were self-assembled on InP substrate by using metal–organic chemical vapor deposition (MOCVD). Instead of using arsine, the safer organic tert-butylarsine (TBAs) was used as the arsenic source in the growth process. Effects of the growth conditions, i.e. substrate temperature and the growth rate, on the InAsSb QD formations have been studied. A narrow temperature window from 450 °C to 470 °C was found for growing high quality InAsSb QDs. InAsSb rings instead of islands/dots were formed using the conventional Stranski–Krastanow (S–K) growth mode if the growth rate was low or if InAsSb was grown for a longer time. By increasing the V : III ratio for the InAsSb growth, InAsSb islands/dots were formed with the same growth rate. To reduce the dot size and increase the InAsSb QD density, an alternative interruption growth (AIG) method was proposed and investigated. Using the AIG growth method, much higher dot density of the InAsSb QDs has been achieved, about 3 × 109 cm−2, which is about 10 times of that of the QDs grown by using the conventional S–K growth method. Strong photoluminescence emissions of the InAsSb islands/dots were observed. At room temperature, the emission wavelength of the InAsSb islands/dots was measured at >2.8 μm. ASTAR (Agency for Sci., Tech. and Research, S’pore) Accepted version 2016-01-22T07:38:47Z 2019-12-06T14:46:02Z 2016-01-22T07:38:47Z 2019-12-06T14:46:02Z 2012 Journal Article Tang, X., Zhang, B., & Yin, Z. (2013). Mid-infrared emissive InAsSb quantum dots grown by metal–organic chemical vapor deposition. CrystEngComm, 15(3), 604-608. 1466-8033 https://hdl.handle.net/10356/82076 http://hdl.handle.net/10220/39757 10.1039/C2CE26271A en CrystEngComm © 2013 The Royal Society of Chemistry. This is the author created version of a work that has been peer reviewed and accepted for publication by CrystEngComm, The Royal Society of Chemistry. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1039/C2CE26271A]. 12 p. application/pdf
spellingShingle Quantum dots
Tang, Xiaohong
Zhang, Baolin
Yin, Zongyou
Mid-infrared emissive InAsSb quantum dots grown by metal–organic chemical vapor deposition
title Mid-infrared emissive InAsSb quantum dots grown by metal–organic chemical vapor deposition
title_full Mid-infrared emissive InAsSb quantum dots grown by metal–organic chemical vapor deposition
title_fullStr Mid-infrared emissive InAsSb quantum dots grown by metal–organic chemical vapor deposition
title_full_unstemmed Mid-infrared emissive InAsSb quantum dots grown by metal–organic chemical vapor deposition
title_short Mid-infrared emissive InAsSb quantum dots grown by metal–organic chemical vapor deposition
title_sort mid infrared emissive inassb quantum dots grown by metal organic chemical vapor deposition
topic Quantum dots
url https://hdl.handle.net/10356/82076
http://hdl.handle.net/10220/39757
work_keys_str_mv AT tangxiaohong midinfraredemissiveinassbquantumdotsgrownbymetalorganicchemicalvapordeposition
AT zhangbaolin midinfraredemissiveinassbquantumdotsgrownbymetalorganicchemicalvapordeposition
AT yinzongyou midinfraredemissiveinassbquantumdotsgrownbymetalorganicchemicalvapordeposition