Consolidation of B4C–VB2 eutectic ceramics by spark plasma sintering
The in situ synthesis and consolidation of B4C–VB2 eutectic composites by spark plasma sintering (SPS) is reported. The microstructure properties were determined for composites with the B4C–VB2 eutectic composition as functions of the VB2 content and the VB2–VB2 interlamellar spacing. A change of VB...
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2016
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Online Access: | https://hdl.handle.net/10356/83817 http://hdl.handle.net/10220/41449 |
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author | Demirskyi, Dmytro Sakka, Yoshio Vasylkiv, Oleg |
author2 | Temasek Laboratories |
author_facet | Temasek Laboratories Demirskyi, Dmytro Sakka, Yoshio Vasylkiv, Oleg |
author_sort | Demirskyi, Dmytro |
collection | NTU |
description | The in situ synthesis and consolidation of B4C–VB2 eutectic composites by spark plasma sintering (SPS) is reported. The microstructure properties were determined for composites with the B4C–VB2 eutectic composition as functions of the VB2 content and the VB2–VB2 interlamellar spacing. A change of VB2 concentration from 45 to 48 mol.% resulted in the formation of the rod-like eutectic microstructure. Indentation fracture toughness values higher than 4 MPa·m1/2 were identified for eutectic composites with interlamellar spacings between 0.9 and 1.2 µm. The composites obtained by SPS with a composition of 45 mol.% VB2 exhibited a lower Vickers hardness (23–24 GPa) and higher indentation fracture toughness (up to 4.5 MPa·m1/2) than the eutectic composites with 48 mol.% of VB2. |
first_indexed | 2024-10-01T02:48:21Z |
format | Journal Article |
id | ntu-10356/83817 |
institution | Nanyang Technological University |
language | English |
last_indexed | 2024-10-01T02:48:21Z |
publishDate | 2016 |
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spelling | ntu-10356/838172020-09-26T22:16:33Z Consolidation of B4C–VB2 eutectic ceramics by spark plasma sintering Demirskyi, Dmytro Sakka, Yoshio Vasylkiv, Oleg Temasek Laboratories Spark plasma sintering Boron carbide The in situ synthesis and consolidation of B4C–VB2 eutectic composites by spark plasma sintering (SPS) is reported. The microstructure properties were determined for composites with the B4C–VB2 eutectic composition as functions of the VB2 content and the VB2–VB2 interlamellar spacing. A change of VB2 concentration from 45 to 48 mol.% resulted in the formation of the rod-like eutectic microstructure. Indentation fracture toughness values higher than 4 MPa·m1/2 were identified for eutectic composites with interlamellar spacings between 0.9 and 1.2 µm. The composites obtained by SPS with a composition of 45 mol.% VB2 exhibited a lower Vickers hardness (23–24 GPa) and higher indentation fracture toughness (up to 4.5 MPa·m1/2) than the eutectic composites with 48 mol.% of VB2. Published version 2016-09-16T03:38:43Z 2019-12-06T15:32:41Z 2016-09-16T03:38:43Z 2019-12-06T15:32:41Z 2015 Journal Article Demirskyi, D., Sakka, Y., & Vasylkiv, O. (2015). Consolidation of B4C–VB2 eutectic ceramics by spark plasma sintering. Journal of the Ceramic Society of Japan, 123(1443), 1051-1054. 1882-0743 https://hdl.handle.net/10356/83817 http://hdl.handle.net/10220/41449 10.2109/jcersj2.123.1051 en Journal of the Ceramic Society of Japan © 2015 The Ceramic Society of Japan. This paper was published in Journal of the Ceramic Society of Japan and is made available as an electronic reprint (preprint) with permission of The Ceramic Society of Japan. The published version is available at: [http://doi.org/10.2109/jcersj2.123.1051]. One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper is prohibited and is subject to penalties under law. 4 p. application/pdf |
spellingShingle | Spark plasma sintering Boron carbide Demirskyi, Dmytro Sakka, Yoshio Vasylkiv, Oleg Consolidation of B4C–VB2 eutectic ceramics by spark plasma sintering |
title | Consolidation of B4C–VB2 eutectic ceramics by spark plasma sintering |
title_full | Consolidation of B4C–VB2 eutectic ceramics by spark plasma sintering |
title_fullStr | Consolidation of B4C–VB2 eutectic ceramics by spark plasma sintering |
title_full_unstemmed | Consolidation of B4C–VB2 eutectic ceramics by spark plasma sintering |
title_short | Consolidation of B4C–VB2 eutectic ceramics by spark plasma sintering |
title_sort | consolidation of b4c vb2 eutectic ceramics by spark plasma sintering |
topic | Spark plasma sintering Boron carbide |
url | https://hdl.handle.net/10356/83817 http://hdl.handle.net/10220/41449 |
work_keys_str_mv | AT demirskyidmytro consolidationofb4cvb2eutecticceramicsbysparkplasmasintering AT sakkayoshio consolidationofb4cvb2eutecticceramicsbysparkplasmasintering AT vasylkivoleg consolidationofb4cvb2eutecticceramicsbysparkplasmasintering |