Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts
Pt nanoparticles supported on multiwalled carbon nanotubes (MWNT) were synthesized and applied in the catalytic hydrogenation of furfural, the model reaction of mild stabilization of reactive bio-oil. The catalytic properties of the catalysts were modified by changing the surface concentration of ox...
Main Authors: | , , , , |
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Format: | Journal Article |
Language: | English |
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2016
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Online Access: | https://hdl.handle.net/10356/83852 http://hdl.handle.net/10220/41493 |
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author | Wang, Chuan Guo, Zhen Yang, Yanhui Chang, Jie Borgna, Armando |
author2 | School of Chemical and Biomedical Engineering |
author_facet | School of Chemical and Biomedical Engineering Wang, Chuan Guo, Zhen Yang, Yanhui Chang, Jie Borgna, Armando |
author_sort | Wang, Chuan |
collection | NTU |
description | Pt nanoparticles supported on multiwalled carbon nanotubes (MWNT) were synthesized and applied in the catalytic hydrogenation of furfural, the model reaction of mild stabilization of reactive bio-oil. The catalytic properties of the catalysts were modified by changing the surface concentration of oxygen-containing groups (OCGs) of MWNT. Various characterization techniques, including fluorescent labeling, nitrogen physisorption, powder X-ray diffraction, transmission electron microscopy, and in situ DRIFTS analysis, were employed to study both the supports and catalysts. Pt nanoparticles supported on MWNT with high OCGs show high activity and selectivity, attributed to the formation of small Pt particles as a result of the high concentration of OCGs. |
first_indexed | 2024-10-01T06:58:43Z |
format | Journal Article |
id | ntu-10356/83852 |
institution | Nanyang Technological University |
language | English |
last_indexed | 2024-10-01T06:58:43Z |
publishDate | 2016 |
record_format | dspace |
spelling | ntu-10356/838522020-03-07T11:35:33Z Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts Wang, Chuan Guo, Zhen Yang, Yanhui Chang, Jie Borgna, Armando School of Chemical and Biomedical Engineering Furfural Catalytic hydrogenation Pt nanoparticles supported on multiwalled carbon nanotubes (MWNT) were synthesized and applied in the catalytic hydrogenation of furfural, the model reaction of mild stabilization of reactive bio-oil. The catalytic properties of the catalysts were modified by changing the surface concentration of oxygen-containing groups (OCGs) of MWNT. Various characterization techniques, including fluorescent labeling, nitrogen physisorption, powder X-ray diffraction, transmission electron microscopy, and in situ DRIFTS analysis, were employed to study both the supports and catalysts. Pt nanoparticles supported on MWNT with high OCGs show high activity and selectivity, attributed to the formation of small Pt particles as a result of the high concentration of OCGs. ASTAR (Agency for Sci., Tech. and Research, S’pore) 2016-09-26T05:45:38Z 2019-12-06T15:33:12Z 2016-09-26T05:45:38Z 2019-12-06T15:33:12Z 2014 Journal Article Wang, C., Guo, Z., Yang, Y., Chang, J., & Borgna, A. (2014). Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts. Industrial & Engineering Chemistry Research, 53(28), 11284-11291. 0888-5885 https://hdl.handle.net/10356/83852 http://hdl.handle.net/10220/41493 10.1021/ie501057t en Industrial & Engineering Chemistry Research © 2014 American Chemical Society. |
spellingShingle | Furfural Catalytic hydrogenation Wang, Chuan Guo, Zhen Yang, Yanhui Chang, Jie Borgna, Armando Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts |
title | Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts |
title_full | Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts |
title_fullStr | Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts |
title_full_unstemmed | Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts |
title_short | Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts |
title_sort | hydrogenation of furfural as model reaction of bio oil stabilization under mild conditions using multiwalled carbon nanotube mwnt supported pt catalysts |
topic | Furfural Catalytic hydrogenation |
url | https://hdl.handle.net/10356/83852 http://hdl.handle.net/10220/41493 |
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