Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts

Pt nanoparticles supported on multiwalled carbon nanotubes (MWNT) were synthesized and applied in the catalytic hydrogenation of furfural, the model reaction of mild stabilization of reactive bio-oil. The catalytic properties of the catalysts were modified by changing the surface concentration of ox...

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Main Authors: Wang, Chuan, Guo, Zhen, Yang, Yanhui, Chang, Jie, Borgna, Armando
Other Authors: School of Chemical and Biomedical Engineering
Format: Journal Article
Language:English
Published: 2016
Subjects:
Online Access:https://hdl.handle.net/10356/83852
http://hdl.handle.net/10220/41493
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author Wang, Chuan
Guo, Zhen
Yang, Yanhui
Chang, Jie
Borgna, Armando
author2 School of Chemical and Biomedical Engineering
author_facet School of Chemical and Biomedical Engineering
Wang, Chuan
Guo, Zhen
Yang, Yanhui
Chang, Jie
Borgna, Armando
author_sort Wang, Chuan
collection NTU
description Pt nanoparticles supported on multiwalled carbon nanotubes (MWNT) were synthesized and applied in the catalytic hydrogenation of furfural, the model reaction of mild stabilization of reactive bio-oil. The catalytic properties of the catalysts were modified by changing the surface concentration of oxygen-containing groups (OCGs) of MWNT. Various characterization techniques, including fluorescent labeling, nitrogen physisorption, powder X-ray diffraction, transmission electron microscopy, and in situ DRIFTS analysis, were employed to study both the supports and catalysts. Pt nanoparticles supported on MWNT with high OCGs show high activity and selectivity, attributed to the formation of small Pt particles as a result of the high concentration of OCGs.
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spelling ntu-10356/838522020-03-07T11:35:33Z Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts Wang, Chuan Guo, Zhen Yang, Yanhui Chang, Jie Borgna, Armando School of Chemical and Biomedical Engineering Furfural Catalytic hydrogenation Pt nanoparticles supported on multiwalled carbon nanotubes (MWNT) were synthesized and applied in the catalytic hydrogenation of furfural, the model reaction of mild stabilization of reactive bio-oil. The catalytic properties of the catalysts were modified by changing the surface concentration of oxygen-containing groups (OCGs) of MWNT. Various characterization techniques, including fluorescent labeling, nitrogen physisorption, powder X-ray diffraction, transmission electron microscopy, and in situ DRIFTS analysis, were employed to study both the supports and catalysts. Pt nanoparticles supported on MWNT with high OCGs show high activity and selectivity, attributed to the formation of small Pt particles as a result of the high concentration of OCGs. ASTAR (Agency for Sci., Tech. and Research, S’pore) 2016-09-26T05:45:38Z 2019-12-06T15:33:12Z 2016-09-26T05:45:38Z 2019-12-06T15:33:12Z 2014 Journal Article Wang, C., Guo, Z., Yang, Y., Chang, J., & Borgna, A. (2014). Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts. Industrial & Engineering Chemistry Research, 53(28), 11284-11291. 0888-5885 https://hdl.handle.net/10356/83852 http://hdl.handle.net/10220/41493 10.1021/ie501057t en Industrial & Engineering Chemistry Research © 2014 American Chemical Society.
spellingShingle Furfural
Catalytic hydrogenation
Wang, Chuan
Guo, Zhen
Yang, Yanhui
Chang, Jie
Borgna, Armando
Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts
title Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts
title_full Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts
title_fullStr Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts
title_full_unstemmed Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts
title_short Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts
title_sort hydrogenation of furfural as model reaction of bio oil stabilization under mild conditions using multiwalled carbon nanotube mwnt supported pt catalysts
topic Furfural
Catalytic hydrogenation
url https://hdl.handle.net/10356/83852
http://hdl.handle.net/10220/41493
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