General Formation of MxCo3−xS4 (M=Ni, Mn, Zn) Hollow Tubular Structures for Hybrid Supercapacitors
A simple and versatile method for general synthesis of uniform one-dimensional (1D) MxCo3−xS4 (M=Ni, Mn, Zn) hollow tubular structures (HTSs), using soft polymeric nanofibers as a template, is described. Fibrous core–shell polymer@M-Co acetate hydroxide precursors with a controllable molar ratio of...
| Main Authors: | , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2017
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| Online Access: | https://hdl.handle.net/10356/85736 http://hdl.handle.net/10220/43826 |
| _version_ | 1811683083130241024 |
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| author | Chen, Yu Ming Li, Zhen Lou, Xiong Wen David |
| author2 | School of Chemical and Biomedical Engineering |
| author_facet | School of Chemical and Biomedical Engineering Chen, Yu Ming Li, Zhen Lou, Xiong Wen David |
| author_sort | Chen, Yu Ming |
| collection | NTU |
| description | A simple and versatile method for general synthesis of uniform one-dimensional (1D) MxCo3−xS4 (M=Ni, Mn, Zn) hollow tubular structures (HTSs), using soft polymeric nanofibers as a template, is described. Fibrous core–shell polymer@M-Co acetate hydroxide precursors with a controllable molar ratio of M/Co are first prepared, followed by a sulfidation process to obtain core–shell polymer@MxCo3−xS4 composite nanofibers. The as-made MxCo3−xS4 HTSs have a high surface area and exhibit exceptional electrochemical performance as electrode materials for hybrid supercapacitors. For example, the MnCo2S4 HTS electrode can deliver specific capacitance of 1094 F g−1 at 10 A g−1, and the cycling stability is remarkable, with only about 6 % loss over 20 000 cycles. |
| first_indexed | 2024-10-01T04:07:05Z |
| format | Journal Article |
| id | ntu-10356/85736 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T04:07:05Z |
| publishDate | 2017 |
| record_format | dspace |
| spelling | ntu-10356/857362020-03-07T11:35:28Z General Formation of MxCo3−xS4 (M=Ni, Mn, Zn) Hollow Tubular Structures for Hybrid Supercapacitors Chen, Yu Ming Li, Zhen Lou, Xiong Wen David School of Chemical and Biomedical Engineering Mixed Metal Sulfides Nanotubes A simple and versatile method for general synthesis of uniform one-dimensional (1D) MxCo3−xS4 (M=Ni, Mn, Zn) hollow tubular structures (HTSs), using soft polymeric nanofibers as a template, is described. Fibrous core–shell polymer@M-Co acetate hydroxide precursors with a controllable molar ratio of M/Co are first prepared, followed by a sulfidation process to obtain core–shell polymer@MxCo3−xS4 composite nanofibers. The as-made MxCo3−xS4 HTSs have a high surface area and exhibit exceptional electrochemical performance as electrode materials for hybrid supercapacitors. For example, the MnCo2S4 HTS electrode can deliver specific capacitance of 1094 F g−1 at 10 A g−1, and the cycling stability is remarkable, with only about 6 % loss over 20 000 cycles. MOE (Min. of Education, S’pore) 2017-10-02T06:42:46Z 2019-12-06T16:09:18Z 2017-10-02T06:42:46Z 2019-12-06T16:09:18Z 2015 Journal Article Chen, Y. M., Li, Z., & Lou, X. W. D. (2015). General Formation of MxCo3−xS4 (M=Ni, Mn, Zn) Hollow Tubular Structures for Hybrid Supercapacitors. Angewandte Chemie International Edition, 54(36), 10521-10524. 1433-7851 https://hdl.handle.net/10356/85736 http://hdl.handle.net/10220/43826 10.1002/anie.201504349 en Angewandte Chemie International Edition © 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| spellingShingle | Mixed Metal Sulfides Nanotubes Chen, Yu Ming Li, Zhen Lou, Xiong Wen David General Formation of MxCo3−xS4 (M=Ni, Mn, Zn) Hollow Tubular Structures for Hybrid Supercapacitors |
| title | General Formation of MxCo3−xS4 (M=Ni, Mn, Zn) Hollow Tubular Structures for Hybrid Supercapacitors |
| title_full | General Formation of MxCo3−xS4 (M=Ni, Mn, Zn) Hollow Tubular Structures for Hybrid Supercapacitors |
| title_fullStr | General Formation of MxCo3−xS4 (M=Ni, Mn, Zn) Hollow Tubular Structures for Hybrid Supercapacitors |
| title_full_unstemmed | General Formation of MxCo3−xS4 (M=Ni, Mn, Zn) Hollow Tubular Structures for Hybrid Supercapacitors |
| title_short | General Formation of MxCo3−xS4 (M=Ni, Mn, Zn) Hollow Tubular Structures for Hybrid Supercapacitors |
| title_sort | general formation of mxco3 xs4 m ni mn zn hollow tubular structures for hybrid supercapacitors |
| topic | Mixed Metal Sulfides Nanotubes |
| url | https://hdl.handle.net/10356/85736 http://hdl.handle.net/10220/43826 |
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