Stabilization of superoxocopper(II) and oxoiron(IV) complexes using bulky bis- and tris(2-pyridylmethyl)amine ligand

Stabilization of superoxocopper(II) and oxoiron(IV) complexes using bulky bis- and tris(2-pyridylmethyl)amine ligand

Highly reactive ‘end-on’ superoxocopper(II) and oxoiron(IV) intermediates are recognized as active oxidants responsible for substrate C-H bond hydroxylation in a wide range of non-heme metalloenzymes. Mimicking such reactivity in synthetic systems would provide a major improvement over the current d...

Bibliografske podrobnosti
Glavni avtor:	Quek, Sebastian Yongsen
Drugi avtorji:	Jason England
Format:	Thesis
Jezik:	English
Izdano:	2019
Teme:	Science::Chemistry
Online dostop:	https://hdl.handle.net/10356/86178 http://hdl.handle.net/10220/49273

Podobne knjige/članki

Tris(2-pyridylmethyl)amine (TPA) as a membrane-permeable chelator for interception of biological mobile zinc
od: Huang, Zhen, et al.
Izdano: (2015)

Synthesis and reactivity of bioinspired superoxocopper(II) complexes
od: Laxmi, Shoba
Izdano: (2022)

mu-Acetato-bis(mu-2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl)amin o]methyl}phenolato)dinickel(II) chloride
od: Tiekink, E.R.T., et al.
Izdano: (2010)

Sterically stabilized end-on superoxocopper(II) complexes and mechanistic insights into their reactivity with O−H, N−H, and C−H substrates
od: Quek, Sebastian Y., et al.
Izdano: (2022)

σ-Bonded organochromium(III) complexes. 3. decomposition in acid solution of chromium(III) complexes containing pyridylmethyl and polydentate amine ligands
od: Crouse, Karen, et al.
Izdano: (1986)

Poly[[bis[mu(2)-N,N `-bis(2-pyridylmethyl)-oxalamide-kappa N-4,O:N `,O `][mu(2)-N,' N-bis(2-pyridylmethyl)oxalamide-kappa N-2:N `]disilver(I)] bis(trifluoromethanesulfonate)]
od: Arman, H.D., et al.
Izdano: (2010)

AshPhos Ligand: Facilitating Challenging Aminations in Five- and Six-Membered Heteroaryl Halides Using Cyclic Secondary and Bulky Amines
od: Ashish Dusunge, et al.
Izdano: (2024-12-01)

Synthesis of Cyclometallated Pt(II) Complexes of a Bulky Bipyridine Ligand
od: Sarath D. Perera
Izdano: (2020-06-01)

2,2 `-(Disulfanediyl)dibenzoic acid-N,N `-bis(3-pyridylmethyl)ethanediamide (1/1)
od: Arman, H.D., et al.
Izdano: (2010)

2,2 `-(Disulfanediyl)dibenzoic acid-N,N `-bis(4-pyridylmethyl)ethanedithioamide (1/1)
od: Arman, H.D., et al.
Izdano: (2010)

Synthesis of new bulky bis(pyrazolyl)methane carboxylate (heteroscorpionate) ligands and their complexes with iron, manganese and nickel.
od: Jones, M, et al.
Izdano: (2012)

Stereoisomeric Tris-BINOL-Menthol Bulky Monophosphites: Synthesis, Characterisation and Application in Rhodium-Catalysed Hydroformylation
od: Alexandre P. Felgueiras, et al.
Izdano: (2022-03-01)

Synthesis of a New Class of Tris- and Bis(1,3,4-thiadiazol-2-amine) Methyl and Ethyl Tris- and Bis-2-(2-(2-benzoyl hydrazinyl)-4-oxothiazolidine) Acetate Derivatives
od: Ali Darehkordi, et al.
Izdano: (2013-01-01)

The structure of bis (isopropylthioacetato) tris (isoquinoline) copper (II) - potentially heptacoordinated complex /
od: Yoshyuki Sato

Potassium, zinc, and magnesium complexes of a bulky OOO-tridentate bis(phenolate) ligand: synthesis, structures, and studies of cyclic ester polymerisation.
od: Huang, Y, et al.
Izdano: (2013)

Synthesis, Crystal Structure, and DNA-Binding Studies of a Nickel(II) Complex with the Bis(2-benzimidazolymethyl)amine Ligand
od: Huilu Wu, et al.
Izdano: (2012-01-01)

Bulky aryl functionalized carbazolyl ligands: amido alternatives to the 2,6-diarylphenyl ligand class?
od: Coombs, N, et al.
Izdano: (2008)

Aluminum Dimer Containing Bulky 1,2,3-Triazolate Ligand
od: Issam Kobrsi
Izdano: (2014-01-01)

Synthesis and characterization of novel organometallic chromium hexacarbonyl derivatives via ligand (L) substitution, where L = tris (3-methylphenyl) arsine, tris (M-fluorophenyl) phosphine and tris [3, 5-Bis (trifluoromethyl) phenyl] phosphine
od: Muhammad Yazid, Mohamad Yunus
Izdano: (2012)

Tris{2-[(2,6-dimethylphenyl)amino]ethyl}amine
od: Moroz, Yurii S., et al.
Izdano: (2014)

Bis[tris(diisobutyldithiocarbamato)-μ3-sulfido-tri-μ2-disulfido-trimolybdenum(IV)] sulfide tetrahydrofuran monosolvate
od: Addison Fraker, et al.
Izdano: (2024-05-01)

Countercation Effect on CO 2 Binding to Oxo Titanate with Bulky Anilide Ligands
od: Paparo, Albert, et al.
Izdano: (2022)

Iron precatalysts with bulky tri(t‐butyl)cyclopentadienyl ligands for the dehydrocoupling of dimethylamine‐borane
od: Manners, I, et al.
Izdano: (2018)

Structure of the five-coordinate CoII complex (1H-imidazole){tris[(1-benzyltriazol-4-yl-κN3)methyl]amine-κN}cobalt(II) bis(tetrafluoroborate)
od: Vipul Batra, et al.
Izdano: (2024-05-01)

The chemistry of tris [Bis (1,2-Diphenylphosphino) methane] molybdenum/
od: Nor Aziah Buang, eauthor

Synthesis and optical properties of bis- and tris-alkynyl-2-trifluoromethylquinolines
od: Stefan Jopp, et al.
Izdano: (2024-05-01)

Bulky guanidinato and amidinato zinc complexes and their comparative stabilities.
od: Jones, C, et al.
Izdano: (2010)

Molecular structure of tris[(6-bromopyridin-2-yl)methyl]amine
od: Ran Yan, et al.
Izdano: (2024-10-01)

Synthesis and characterization of iron complexes supported by bulky amide ligands : reduction and oxidation chemistry
od: Stokes, Sheree Lynell, 1971-
Izdano: (2005)

Low-valent and low-coordinate titanium and molybdenum complexes supported with bulky amido ligands
od: Johnson, Adam Reid, 1971-
Izdano: (2005)

The first group 4 metal bis(imido) and tris(imido) complexes
od: Schwarz, A, et al.
Izdano: (2012)

The chemistry of tris [Bis (1,2-Diphenylphosphino) methane] molybdenum / [mikrofilem]
od: 194963 Nor Aziah Buang

Finely-Tuned Bis(imino)pyridylcobalt Complexes Enhance Ethylene Polymerization: The Role of Bulky and Halogen Substituents
od: Elizabeth Ogbe, et al.
Izdano: (2025-02-01)

Analysis of the ion mobility spectra of chloroacetophenone, tris(2-chloroethyl)amine, and methanethiol
od: D. A. Aleksandrova, et al.
Izdano: (2024-11-01)

THE SYNTHESIS OF NOVEL SCHIFF-BASE BIS-CROWN AND TRIS-CROWN ETHER LIGANDS CONTAINING RECOGNITION SITES FOR ALKALI AND TRANSITION-METAL GUEST CATIONS
od: Beer, P, et al.
Izdano: (1988)

Renium complexes with the umbrella ligand tris(O-mercaptophenyl)phosphine
od: Daughtry, Sean Keenan, 1971-
Izdano: (2009)

Coordination, organometallic and related chemistry of tris(pyrazolyl)methane ligands.
od: Bigmore, H, et al.
Izdano: (2005)

Oxidative Addition Complexes as Precatalysts for Cross-Coupling Reactions Requiring Extremely Bulky Biarylphosphine Ligands
od: Ingoglia, Bryan Taylor, et al.
Izdano: (2018)

Synthesis and Application of Palladium Precatalysts that Accommodate Extremely Bulky Di-tert-butylphosphino Biaryl Ligands
od: Bruno, Nicholas C., et al.
Izdano: (2015)

Hydrogen Production by the Ruthenium(II) Complex Bearing a Bulky PNP Ligand: A Catalyst for the Decomposition of Formic Acid and/or Ammonium Formate
od: André L. Bogado, et al.
Izdano: (2024-12-01)