Stabilization of superoxocopper(II) and oxoiron(IV) complexes using bulky bis- and tris(2-pyridylmethyl)amine ligand
Highly reactive ‘end-on’ superoxocopper(II) and oxoiron(IV) intermediates are recognized as active oxidants responsible for substrate C-H bond hydroxylation in a wide range of non-heme metalloenzymes. Mimicking such reactivity in synthetic systems would provide a major improvement over the current d...
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| Format: | Thesis |
| Language: | English |
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2019
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| Online Access: | https://hdl.handle.net/10356/86178 http://hdl.handle.net/10220/49273 |