Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates

A cobalt–N-heterocyclic carbene (NHC) catalyst efficiently promotes an ortho C–H alkenylation reaction of pivalophenone N–H imine with an alkenyl phosphate. The reaction tolerates various substituted pivalophenone N–H imines as well as cyclic and acyclic alkenyl phosphates.

Sonraí bibleagrafaíochta
Príomhchruthaitheoirí: Xu, Wengang, Yoshikai, Naohiko
Rannpháirtithe: School of Physical and Mathematical Sciences
Formáid: Journal Article
Teanga:English
Foilsithe / Cruthaithe: 2018
Ábhair:
Rochtain ar líne:https://hdl.handle.net/10356/86228
http://hdl.handle.net/10220/45244
Cur síos
Achoimre:A cobalt–N-heterocyclic carbene (NHC) catalyst efficiently promotes an ortho C–H alkenylation reaction of pivalophenone N–H imine with an alkenyl phosphate. The reaction tolerates various substituted pivalophenone N–H imines as well as cyclic and acyclic alkenyl phosphates.