Asymmetric syntheses of 8-oxabicyclo[3,2,1]octane and 11-oxatricyclo[5.3.1.0]undecane from glycals

Asymmetric syntheses of 8-oxabicyclo[3,2,1]octane and 11-oxatricyclo[5.3.1.0]undecane from glycals

Herein, we describe an efficient method to prepare enantiomerically pure 8-oxabicyclo[3.2.1]octanes via gold(I)-catalyzed tandem 1,3-acyloxy migration/Ferrier rearrangement of glycal derived 1,6-enyne bearing propargylic carboxylates. The resultant compounds could then undergo interrupted Nazarov cy...

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Bibliographic Details
Main Authors:	Liao, Hongze, Leng, Wei-Lin, Hoang, Kim Le Mai, Yao, Hui, He, Jingxi, Voo, Amanda Ying Hui, Liu, Xue-Wei
Other Authors:	School of Physical and Mathematical Sciences
Format:	Journal Article
Language:	English
Published:	2017
Subjects:	Asymmetric Synthesis Glycals
Online Access:	https://hdl.handle.net/10356/86867 http://hdl.handle.net/10220/44230

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