Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions
Nickel-catalyzed addition of arylboron reagents to ketones results in aryl olefins directly. The neutral condition allows acidic protons of alcohols, phenols, and malonates to be present, and fragile structures are also tolerated.
| Main Authors: | , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
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2017
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| Online Access: | https://hdl.handle.net/10356/86882 http://hdl.handle.net/10220/44198 |
| _version_ | 1826112754406129664 |
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| author | Lei, Chuanhu Yip, Yong Jie Zhou, Jianrong Steve |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Lei, Chuanhu Yip, Yong Jie Zhou, Jianrong Steve |
| author_sort | Lei, Chuanhu |
| collection | NTU |
| description | Nickel-catalyzed addition of arylboron reagents to ketones results in aryl olefins directly. The neutral condition allows acidic protons of alcohols, phenols, and malonates to be present, and fragile structures are also tolerated. |
| first_indexed | 2024-10-01T03:12:18Z |
| format | Journal Article |
| id | ntu-10356/86882 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T03:12:18Z |
| publishDate | 2017 |
| record_format | dspace |
| spelling | ntu-10356/868822023-02-28T19:23:40Z Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions Lei, Chuanhu Yip, Yong Jie Zhou, Jianrong Steve School of Physical and Mathematical Sciences Aryl Olefins Ketone Nickel-catalyzed addition of arylboron reagents to ketones results in aryl olefins directly. The neutral condition allows acidic protons of alcohols, phenols, and malonates to be present, and fragile structures are also tolerated. MOE (Min. of Education, S’pore) Accepted version 2017-12-27T04:25:31Z 2019-12-06T16:30:52Z 2017-12-27T04:25:31Z 2019-12-06T16:30:52Z 2017 Journal Article Lei, C., Yip, Y. J., & Zhou, J. S. (2017). Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions. Journal of the American Chemical Society, 139(17), 6086-6089. 0002-7863 https://hdl.handle.net/10356/86882 http://hdl.handle.net/10220/44198 10.1021/jacs.7b02742 en Journal of the American Chemical Society © 2017 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of the American Chemical Society, ACS Publications. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/jacs.7b02742]. 6 p. application/pdf |
| spellingShingle | Aryl Olefins Ketone Lei, Chuanhu Yip, Yong Jie Zhou, Jianrong Steve Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions |
| title | Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions |
| title_full | Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions |
| title_fullStr | Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions |
| title_full_unstemmed | Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions |
| title_short | Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions |
| title_sort | nickel catalyzed direct synthesis of aryl olefins from ketones and organoboron reagents under neutral conditions |
| topic | Aryl Olefins Ketone |
| url | https://hdl.handle.net/10356/86882 http://hdl.handle.net/10220/44198 |
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