Combining the catalytic enantioselective reaction of visible-light-generated radicals with a by-product utilization system
We report an unusual reaction design in which a chiral bis-cyclometalated rhodium(III) complex enables the stereocontrolled chemistry of photo-generated carbon-centered radicals and at the same time catalyzes an enantioselective sulfonyl radical addition to an alkene. Specifically, employing inexpen...
Main Authors: | Huang, Xiaoqiang, Luo, Shipeng, Burghaus, Olaf, Webster, Richard David, Harms, Klaus, Meggers, Eric |
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Other Authors: | School of Physical and Mathematical Sciences |
Format: | Journal Article |
Language: | English |
Published: |
2017
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/86888 http://hdl.handle.net/10220/44207 |
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