Enhancing electrocatalytic hydrogen evolution by nickel salicylaldimine complexes with alkali metal cations in aqueous media

New salicylaldimine nickel complexes, comprising only earth-abundant elements, have been developed for electrocatalytic hydrogen evolution in aqueous media. The second-sphere ether functionalities on the periphery of the complexes enhance the electrocatalytic activity in the presence of alkali metal...

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Main Authors: Shao, Haiyan, Muduli, Subas K., Tran, Phong D., Soo, Han Sen
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2018
Subjects:
Online Access:https://hdl.handle.net/10356/87659
http://hdl.handle.net/10220/46836
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author Shao, Haiyan
Muduli, Subas K.
Tran, Phong D.
Soo, Han Sen
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Shao, Haiyan
Muduli, Subas K.
Tran, Phong D.
Soo, Han Sen
author_sort Shao, Haiyan
collection NTU
description New salicylaldimine nickel complexes, comprising only earth-abundant elements, have been developed for electrocatalytic hydrogen evolution in aqueous media. The second-sphere ether functionalities on the periphery of the complexes enhance the electrocatalytic activity in the presence of alkali metal cations. The electrocatalysts demonstrate improved performances especially in the economical and sustainable seawater reaction medium.
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spelling ntu-10356/876592023-02-28T19:23:44Z Enhancing electrocatalytic hydrogen evolution by nickel salicylaldimine complexes with alkali metal cations in aqueous media Shao, Haiyan Muduli, Subas K. Tran, Phong D. Soo, Han Sen School of Physical and Mathematical Sciences Electrocatalytic Hydrogen Evolution Nickel Complexes DRNTU::Science::Chemistry New salicylaldimine nickel complexes, comprising only earth-abundant elements, have been developed for electrocatalytic hydrogen evolution in aqueous media. The second-sphere ether functionalities on the periphery of the complexes enhance the electrocatalytic activity in the presence of alkali metal cations. The electrocatalysts demonstrate improved performances especially in the economical and sustainable seawater reaction medium. NRF (Natl Research Foundation, S’pore) MOE (Min. of Education, S’pore) Published version 2018-12-05T08:29:39Z 2019-12-06T16:46:39Z 2018-12-05T08:29:39Z 2019-12-06T16:46:39Z 2016 Journal Article Shao, H., Muduli, S. K., Tran, P. D., & Soo, H. S. (2016). Enhancing electrocatalytic hydrogen evolution by nickel salicylaldimine complexes with alkali metal cations in aqueous media. Chemical Communications, 52(14), 2948-2951. doi:10.1039/C5CC09456A 1359-7345 https://hdl.handle.net/10356/87659 http://hdl.handle.net/10220/46836 10.1039/C5CC09456A en Chemical Communications © 2016 The Royal Society of Chemistry. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material and it is not used for commercial purposes. 4 p. application/pdf
spellingShingle Electrocatalytic Hydrogen Evolution
Nickel Complexes
DRNTU::Science::Chemistry
Shao, Haiyan
Muduli, Subas K.
Tran, Phong D.
Soo, Han Sen
Enhancing electrocatalytic hydrogen evolution by nickel salicylaldimine complexes with alkali metal cations in aqueous media
title Enhancing electrocatalytic hydrogen evolution by nickel salicylaldimine complexes with alkali metal cations in aqueous media
title_full Enhancing electrocatalytic hydrogen evolution by nickel salicylaldimine complexes with alkali metal cations in aqueous media
title_fullStr Enhancing electrocatalytic hydrogen evolution by nickel salicylaldimine complexes with alkali metal cations in aqueous media
title_full_unstemmed Enhancing electrocatalytic hydrogen evolution by nickel salicylaldimine complexes with alkali metal cations in aqueous media
title_short Enhancing electrocatalytic hydrogen evolution by nickel salicylaldimine complexes with alkali metal cations in aqueous media
title_sort enhancing electrocatalytic hydrogen evolution by nickel salicylaldimine complexes with alkali metal cations in aqueous media
topic Electrocatalytic Hydrogen Evolution
Nickel Complexes
DRNTU::Science::Chemistry
url https://hdl.handle.net/10356/87659
http://hdl.handle.net/10220/46836
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