Solvent dependent disorder in M2(BzOip)2(H2O)·solvate (M = Co or Zn)
Coordination polymers derived from 5-benzyloxy isophthalic acid (H2BzOip) are rare, with only three reported that do not contain additional bridging ligands, of which two M2(BzOip)2(H2O) (M = Co and Zn) are isomorphous. It was hoped that by varying the solvent system in a reaction between H2BzOip an...
| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
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2018
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| Online Access: | https://hdl.handle.net/10356/87756 http://hdl.handle.net/10220/45540 |
| _version_ | 1811681756611346432 |
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| author | Teat, Simon J. McCormick, Laura J. Morris, Samuel Alexander Morris, Russell E. Slawin, Alexandra M. Z. |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Teat, Simon J. McCormick, Laura J. Morris, Samuel Alexander Morris, Russell E. Slawin, Alexandra M. Z. |
| author_sort | Teat, Simon J. |
| collection | NTU |
| description | Coordination polymers derived from 5-benzyloxy isophthalic acid (H2BzOip) are rare, with only three reported that do not contain additional bridging ligands, of which two M2(BzOip)2(H2O) (M = Co and Zn) are isomorphous. It was hoped that by varying the solvent system in a reaction between H2BzOip and M(OAc)2 (M = Co and Zn), from water to a water/alcohol mixture, coordination polymers of different topology could be formed. Instead, two polymorphs of the existing M2(BzOip)2(H2O) (M = Co and Zn) were isolated from aqueous methanol and aqueous ethanol, in which a small number of guest solvent molecules are present in the crystals. These guest water molecules disrupt the hexaphenyl embrace motif, leading to varying degrees of disorder of the benzyl groups. |
| first_indexed | 2024-10-01T03:46:00Z |
| format | Journal Article |
| id | ntu-10356/87756 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T03:46:00Z |
| publishDate | 2018 |
| record_format | dspace |
| spelling | ntu-10356/877562023-07-14T15:46:43Z Solvent dependent disorder in M2(BzOip)2(H2O)·solvate (M = Co or Zn) Teat, Simon J. McCormick, Laura J. Morris, Samuel Alexander Morris, Russell E. Slawin, Alexandra M. Z. School of Materials Science & Engineering Facility for Analysis, Characterisation, Testing and Simulation X-ray Crystallography Solvothermal Coordination polymers derived from 5-benzyloxy isophthalic acid (H2BzOip) are rare, with only three reported that do not contain additional bridging ligands, of which two M2(BzOip)2(H2O) (M = Co and Zn) are isomorphous. It was hoped that by varying the solvent system in a reaction between H2BzOip and M(OAc)2 (M = Co and Zn), from water to a water/alcohol mixture, coordination polymers of different topology could be formed. Instead, two polymorphs of the existing M2(BzOip)2(H2O) (M = Co and Zn) were isolated from aqueous methanol and aqueous ethanol, in which a small number of guest solvent molecules are present in the crystals. These guest water molecules disrupt the hexaphenyl embrace motif, leading to varying degrees of disorder of the benzyl groups. Published version 2018-08-08T03:16:00Z 2019-12-06T16:48:47Z 2018-08-08T03:16:00Z 2019-12-06T16:48:47Z 2017 Journal Article McCormick, L. J., Morris, S. A., Teat, S. J., Slawin, A. M. Z., & Morris, R. E. (2018). Solvent dependent disorder in M2(BzOip)2(H2O)·solvate (M = Co or Zn). Crystals, 8(1), 6-. 2073-4352 https://hdl.handle.net/10356/87756 http://hdl.handle.net/10220/45540 10.3390/cryst8010006 en Crystals © 2017 The Author(s). Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). 11 p. application/pdf |
| spellingShingle | X-ray Crystallography Solvothermal Teat, Simon J. McCormick, Laura J. Morris, Samuel Alexander Morris, Russell E. Slawin, Alexandra M. Z. Solvent dependent disorder in M2(BzOip)2(H2O)·solvate (M = Co or Zn) |
| title | Solvent dependent disorder in M2(BzOip)2(H2O)·solvate (M = Co or Zn) |
| title_full | Solvent dependent disorder in M2(BzOip)2(H2O)·solvate (M = Co or Zn) |
| title_fullStr | Solvent dependent disorder in M2(BzOip)2(H2O)·solvate (M = Co or Zn) |
| title_full_unstemmed | Solvent dependent disorder in M2(BzOip)2(H2O)·solvate (M = Co or Zn) |
| title_short | Solvent dependent disorder in M2(BzOip)2(H2O)·solvate (M = Co or Zn) |
| title_sort | solvent dependent disorder in m2 bzoip 2 h2o ·solvate m co or zn |
| topic | X-ray Crystallography Solvothermal |
| url | https://hdl.handle.net/10356/87756 http://hdl.handle.net/10220/45540 |
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