Hydrogen peroxide production in a pilot-scale microbial electrolysis cell

A pilot-scale dual-chamber microbial electrolysis cell (MEC) equipped with a carbon gas-diffusion cathode was evaluated for H2O2 production using acetate medium as the electron donor. To assess the effect of cathodic pH on H2O2 yield, the MEC was tested with an anion exchange membrane (AEM) and a ca...

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Main Authors: Sim, Junyoung, Reid, Robertson, Hussain, Abid, An, Junyeong, Lee, Hyung-Sool
Other Authors: School of Civil and Environmental Engineering
Format: Journal Article
Language:English
Published: 2018
Subjects:
Online Access:https://hdl.handle.net/10356/88380
http://hdl.handle.net/10220/45738
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author Sim, Junyoung
Reid, Robertson
Hussain, Abid
An, Junyeong
Lee, Hyung-Sool
author2 School of Civil and Environmental Engineering
author_facet School of Civil and Environmental Engineering
Sim, Junyoung
Reid, Robertson
Hussain, Abid
An, Junyeong
Lee, Hyung-Sool
author_sort Sim, Junyoung
collection NTU
description A pilot-scale dual-chamber microbial electrolysis cell (MEC) equipped with a carbon gas-diffusion cathode was evaluated for H2O2 production using acetate medium as the electron donor. To assess the effect of cathodic pH on H2O2 yield, the MEC was tested with an anion exchange membrane (AEM) and a cation exchange membrane (CEM), respectively. The maximum current density reached 0.94–0.96 A/m2 in the MEC at applied voltage of 0.35–1.9 V, regardless of membranes. The highest H2O2 conversion efficiency was only 7.2 ± 0.09% for the CEM-MEC. This low conversion would be due to further H2O2 reduction to H2O on the cathode or H2O2 decomposition in bulk liquid. This low H2O2 conversion indicates that large-scale MECs are not ideal for production of concentrated H2O2 but could be useful for a sustainable in-situ oxidation process in wastewater treatment.
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spelling ntu-10356/883802020-03-07T11:43:37Z Hydrogen peroxide production in a pilot-scale microbial electrolysis cell Sim, Junyoung Reid, Robertson Hussain, Abid An, Junyeong Lee, Hyung-Sool School of Civil and Environmental Engineering DRNTU::Engineering::Environmental engineering Hydrogen Peroxide Microbial Electrolysis Cells A pilot-scale dual-chamber microbial electrolysis cell (MEC) equipped with a carbon gas-diffusion cathode was evaluated for H2O2 production using acetate medium as the electron donor. To assess the effect of cathodic pH on H2O2 yield, the MEC was tested with an anion exchange membrane (AEM) and a cation exchange membrane (CEM), respectively. The maximum current density reached 0.94–0.96 A/m2 in the MEC at applied voltage of 0.35–1.9 V, regardless of membranes. The highest H2O2 conversion efficiency was only 7.2 ± 0.09% for the CEM-MEC. This low conversion would be due to further H2O2 reduction to H2O on the cathode or H2O2 decomposition in bulk liquid. This low H2O2 conversion indicates that large-scale MECs are not ideal for production of concentrated H2O2 but could be useful for a sustainable in-situ oxidation process in wastewater treatment. Published version 2018-08-29T08:00:05Z 2019-12-06T17:02:00Z 2018-08-29T08:00:05Z 2019-12-06T17:02:00Z 2018 Journal Article Sim, J., Reid, R., Hussain, A., An, J., & Lee, H.-S. (2018). Hydrogen peroxide production in a pilot-scale microbial electrolysis cell. Biotechnology Reports, 19, e00276-. doi:10.1016/j.btre.2018.e00276 https://hdl.handle.net/10356/88380 http://hdl.handle.net/10220/45738 10.1016/j.btre.2018.e00276 en Biotechnology Reports © 2018 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/). 5 p. application/pdf
spellingShingle DRNTU::Engineering::Environmental engineering
Hydrogen Peroxide
Microbial Electrolysis Cells
Sim, Junyoung
Reid, Robertson
Hussain, Abid
An, Junyeong
Lee, Hyung-Sool
Hydrogen peroxide production in a pilot-scale microbial electrolysis cell
title Hydrogen peroxide production in a pilot-scale microbial electrolysis cell
title_full Hydrogen peroxide production in a pilot-scale microbial electrolysis cell
title_fullStr Hydrogen peroxide production in a pilot-scale microbial electrolysis cell
title_full_unstemmed Hydrogen peroxide production in a pilot-scale microbial electrolysis cell
title_short Hydrogen peroxide production in a pilot-scale microbial electrolysis cell
title_sort hydrogen peroxide production in a pilot scale microbial electrolysis cell
topic DRNTU::Engineering::Environmental engineering
Hydrogen Peroxide
Microbial Electrolysis Cells
url https://hdl.handle.net/10356/88380
http://hdl.handle.net/10220/45738
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