Platinum-catalysed ring-opening isomerisation of piperidine cyclopropanes
A range of cyclopropyl‐fused N‐tosyl piperidines have been synthesised and shown to undergo ring‐opening isomerisation on treatment with platinum(II) catalysts. The products can have either an endo‐cyclic or exo‐cyclic double bond. The selectivity is influenced by reaction temperature, solvent and,...
Main Authors: | Barát, Viktor, Kasinathan, Sivarajan, Bates, Roderick Wayland |
---|---|
Other Authors: | School of Physical and Mathematical Sciences |
Format: | Journal Article |
Language: | English |
Published: |
2019
|
Subjects: | |
Online Access: | https://hdl.handle.net/10356/90122 http://hdl.handle.net/10220/48397 |
Similar Items
-
Transient complexity of E. Coli lipidome is explained by fatty acyl synthesis and cyclopropanation
by: Berezhnoy, Nikolay V., et al.
Published: (2023) -
The endo-aza-Michael addition in the synthesis of piperidines and pyrrolidines
by: Bates, Roderick Wayland, et al.
Published: (2020) -
[3+2] Annulation of Donor–Acceptor Cyclopropanes with Vinyl Azides
by: Gandamana, Dhika Aditya, et al.
Published: (2017) -
Strain-release glycosylation using donor-acceptor cyclopropanes: development and applications in carbohydrate synthesis
by: Ding, Han
Published: (2024) -
Application of hydroformylation for the stereoselective synthesis of piperidine alkaloids
by: Sivarajan Kasinathan
Published: (2014)