Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing
An unexpected “kinked” N-heteroacene with a slipped two-dimensional ladder-like packing feature is produced from the conventional condensation reaction. The as-obtained compound [2,2′]bi(5,12-bis(TIPS)piperazin-3-one[2,3-b]phenazine) (2BPP) consists of two identical backbones (5,12-bis(TIPS)piperazi...
| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
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2018
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| Online Access: | https://hdl.handle.net/10356/90202 http://hdl.handle.net/10220/47187 |
| _version_ | 1811690847902629888 |
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| author | Zhang, Jing Wang, Chengyuan Long, Guankui Aratani, Naoki Yamada, Hiroko Zhang, Qichun |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Zhang, Jing Wang, Chengyuan Long, Guankui Aratani, Naoki Yamada, Hiroko Zhang, Qichun |
| author_sort | Zhang, Jing |
| collection | NTU |
| description | An unexpected “kinked” N-heteroacene with a slipped two-dimensional ladder-like packing feature is produced from the conventional condensation reaction. The as-obtained compound [2,2′]bi(5,12-bis(TIPS)piperazin-3-one[2,3-b]phenazine) (2BPP) consists of two identical backbones (5,12-bis(TIPS)piperazin-3-one[2,3-b]phenazine), which are fused together through a C[double bond, length as m-dash]C double bond and two intramolecular H-bonds. A study on the charge carrier transport indicates that a 2BPP single crystal has a hole mobility up to 0.3 cm2 V−1 s−1, while theoretical calculations suggest that this compound might possess potential well-balanced ambipolar charge-transport characteristics. |
| first_indexed | 2024-10-01T06:10:30Z |
| format | Journal Article |
| id | ntu-10356/90202 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T06:10:30Z |
| publishDate | 2018 |
| record_format | dspace |
| spelling | ntu-10356/902022023-07-14T15:52:54Z Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing Zhang, Jing Wang, Chengyuan Long, Guankui Aratani, Naoki Yamada, Hiroko Zhang, Qichun School of Materials Science & Engineering School of Physical and Mathematical Sciences Carrier Transport Hole Mobility DRNTU::Engineering::Materials An unexpected “kinked” N-heteroacene with a slipped two-dimensional ladder-like packing feature is produced from the conventional condensation reaction. The as-obtained compound [2,2′]bi(5,12-bis(TIPS)piperazin-3-one[2,3-b]phenazine) (2BPP) consists of two identical backbones (5,12-bis(TIPS)piperazin-3-one[2,3-b]phenazine), which are fused together through a C[double bond, length as m-dash]C double bond and two intramolecular H-bonds. A study on the charge carrier transport indicates that a 2BPP single crystal has a hole mobility up to 0.3 cm2 V−1 s−1, while theoretical calculations suggest that this compound might possess potential well-balanced ambipolar charge-transport characteristics. NRF (Natl Research Foundation, S’pore) MOE (Min. of Education, S’pore) Published version 2018-12-24T04:52:56Z 2019-12-06T17:43:00Z 2018-12-24T04:52:56Z 2019-12-06T17:43:00Z 2016 Journal Article Zhang, J., Wang, C., Long, G., Aratani, N., Yamada, H., & Zhang, Q. (2016). Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing. Chemical Science, 7(2), 1309-1313. doi:10.1039/C5SC03604F 2041-6520 https://hdl.handle.net/10356/90202 http://hdl.handle.net/10220/47187 10.1039/C5SC03604F en Chemical Science © 2016 The Author(s) (published by Royal Society of Chemistry). This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. 5 p. application/pdf |
| spellingShingle | Carrier Transport Hole Mobility DRNTU::Engineering::Materials Zhang, Jing Wang, Chengyuan Long, Guankui Aratani, Naoki Yamada, Hiroko Zhang, Qichun Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing |
| title | Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing |
| title_full | Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing |
| title_fullStr | Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing |
| title_full_unstemmed | Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing |
| title_short | Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing |
| title_sort | fusing n heteroacene analogues into one kinked molecule with slipped two dimensional ladder like packing |
| topic | Carrier Transport Hole Mobility DRNTU::Engineering::Materials |
| url | https://hdl.handle.net/10356/90202 http://hdl.handle.net/10220/47187 |
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