Hybrid supercapacitor with nano-TiP2O7 as intercalation electrode
Nano-size (≤ 100 nm) TiP2O7 is prepared by the urea assisted combustion synthesis, at 450 oC and 900 oC. The compound is characterized by powder X-ray diffraction, Rietveld refinement, high resolution transmission electron microscopy and surface area methods. Lithium cycling properties by way of gal...
| Main Authors: | , , , , , |
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| Format: | Journal Article |
| Language: | English |
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2011
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| Online Access: | https://hdl.handle.net/10356/90375 http://hdl.handle.net/10220/6912 |
| _version_ | 1826129134973091840 |
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| author | Aravindan, Vanchiappan Madhavi, Srinivasan Mhaisalkar, Subodh Gautam Rao, G. V. Subba Chowdari, Bobba V. R. Reddy, M. V. |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Aravindan, Vanchiappan Madhavi, Srinivasan Mhaisalkar, Subodh Gautam Rao, G. V. Subba Chowdari, Bobba V. R. Reddy, M. V. |
| author_sort | Aravindan, Vanchiappan |
| collection | NTU |
| description | Nano-size (≤ 100 nm) TiP2O7 is prepared by the urea assisted combustion synthesis, at 450 oC and 900 oC. The compound is characterized by powder X-ray diffraction, Rietveld refinement, high resolution transmission electron microscopy and surface area methods. Lithium cycling properties by way of galvanostaic cycling and cyclic voltammetry (CV) showed a reversible and stable capacity of 60 (± 3) mAh g–1 (0.5 mole of Li) up to 100 cycles, when cycled at 15 mA g–1 between 2-3.5 V vs. Li. Non-aqueous hybrid supercapacitor, TiP2O7 (as anode) and activated carbon (AC) (as cathode) has been studied by galvanostatic cycling and CV in the range, 0-3 V at 31 mA g–1 and exhibited a specific discharge capacitance of 29 (± 1) F g–1stable in the range, 100-500 cycles. The Ragone plot shows a deliverable maximum of 13 Wh kg–1 and 371 W kg–1 energy and power density, respectively. |
| first_indexed | 2024-10-01T07:35:45Z |
| format | Journal Article |
| id | ntu-10356/90375 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T07:35:45Z |
| publishDate | 2011 |
| record_format | dspace |
| spelling | ntu-10356/903752023-07-14T15:49:25Z Hybrid supercapacitor with nano-TiP2O7 as intercalation electrode Aravindan, Vanchiappan Madhavi, Srinivasan Mhaisalkar, Subodh Gautam Rao, G. V. Subba Chowdari, Bobba V. R. Reddy, M. V. School of Materials Science & Engineering DRNTU::Engineering::Materials::Microelectronics and semiconductor materials Nano-size (≤ 100 nm) TiP2O7 is prepared by the urea assisted combustion synthesis, at 450 oC and 900 oC. The compound is characterized by powder X-ray diffraction, Rietveld refinement, high resolution transmission electron microscopy and surface area methods. Lithium cycling properties by way of galvanostaic cycling and cyclic voltammetry (CV) showed a reversible and stable capacity of 60 (± 3) mAh g–1 (0.5 mole of Li) up to 100 cycles, when cycled at 15 mA g–1 between 2-3.5 V vs. Li. Non-aqueous hybrid supercapacitor, TiP2O7 (as anode) and activated carbon (AC) (as cathode) has been studied by galvanostatic cycling and CV in the range, 0-3 V at 31 mA g–1 and exhibited a specific discharge capacitance of 29 (± 1) F g–1stable in the range, 100-500 cycles. The Ragone plot shows a deliverable maximum of 13 Wh kg–1 and 371 W kg–1 energy and power density, respectively. Accepted version 2011-07-18T06:52:43Z 2019-12-06T17:46:41Z 2011-07-18T06:52:43Z 2019-12-06T17:46:41Z 2011 2011 Journal Article Aravindan, V., Reddy, M. V., Madhavi, S., Mhaisalkar, S. G., Rao G. V. S., Chowdari, B. V. R., Hybrid supercapacitor with nano-TiP2O7 as intercalation electrode. Journal of power sources. 0378-7753 https://hdl.handle.net/10356/90375 http://hdl.handle.net/10220/6912 10.1016/j.jpowsour.2011.05.074 160639 en Journal of power sources © 2011 Elsevier. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of Power Sources, Elsevier. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: http://dx.doi.org/10.1016/j.jpowsour.2011.05.074. 23 p. application/pdf |
| spellingShingle | DRNTU::Engineering::Materials::Microelectronics and semiconductor materials Aravindan, Vanchiappan Madhavi, Srinivasan Mhaisalkar, Subodh Gautam Rao, G. V. Subba Chowdari, Bobba V. R. Reddy, M. V. Hybrid supercapacitor with nano-TiP2O7 as intercalation electrode |
| title | Hybrid supercapacitor with nano-TiP2O7 as intercalation electrode |
| title_full | Hybrid supercapacitor with nano-TiP2O7 as intercalation electrode |
| title_fullStr | Hybrid supercapacitor with nano-TiP2O7 as intercalation electrode |
| title_full_unstemmed | Hybrid supercapacitor with nano-TiP2O7 as intercalation electrode |
| title_short | Hybrid supercapacitor with nano-TiP2O7 as intercalation electrode |
| title_sort | hybrid supercapacitor with nano tip2o7 as intercalation electrode |
| topic | DRNTU::Engineering::Materials::Microelectronics and semiconductor materials |
| url | https://hdl.handle.net/10356/90375 http://hdl.handle.net/10220/6912 |
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