Semiconductor nanocomposites of emissive flexible random copolymers and CdTe nanocrystals : preparation, characterization, and optoelectronic properties
Synthesis and characterization of a series of new emissive flexible copolymers composed of two kinds of special side-chain functional groups is demonstrated. One of the side-chain groups provides emissive properties, while the other serves as the ligand unit. The copolymers are used to prepare a new...
Main Authors: | , , , , , , , , |
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Format: | Journal Article |
Language: | English |
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2012
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Online Access: | https://hdl.handle.net/10356/93967 http://hdl.handle.net/10220/8566 |
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author | Qi, Xiaoying Pu, Kan-Yi Fang, Chun Wen, Gui-An Zhang, Hua Boey, Freddy Yin Chiang Fan, Qu-Li Wang, Lianhui Huang, Wei |
author2 | School of Materials Science & Engineering |
author_facet | School of Materials Science & Engineering Qi, Xiaoying Pu, Kan-Yi Fang, Chun Wen, Gui-An Zhang, Hua Boey, Freddy Yin Chiang Fan, Qu-Li Wang, Lianhui Huang, Wei |
author_sort | Qi, Xiaoying |
collection | NTU |
description | Synthesis and characterization of a series of new emissive flexible copolymers composed of two kinds of special side-chain functional groups is demonstrated. One of the side-chain groups provides emissive properties, while the other serves as the ligand unit. The copolymers are used to prepare a new kind of CdTe nanocrystal-based semiconductor nanocomposite. Their structures and morphologies are characterized and their optoelectronic properties are studied. The results reveal that an energy-transfer process from the emissive random copolymers to the CdTe nanocrystals occurs, while a photoinduced charge transfer is estimated to be thermodynamically forbidden. |
first_indexed | 2024-10-01T07:07:13Z |
format | Journal Article |
id | ntu-10356/93967 |
institution | Nanyang Technological University |
language | English |
last_indexed | 2024-10-01T07:07:13Z |
publishDate | 2012 |
record_format | dspace |
spelling | ntu-10356/939672020-06-01T10:21:29Z Semiconductor nanocomposites of emissive flexible random copolymers and CdTe nanocrystals : preparation, characterization, and optoelectronic properties Qi, Xiaoying Pu, Kan-Yi Fang, Chun Wen, Gui-An Zhang, Hua Boey, Freddy Yin Chiang Fan, Qu-Li Wang, Lianhui Huang, Wei School of Materials Science & Engineering DRNTU::Engineering::Materials Synthesis and characterization of a series of new emissive flexible copolymers composed of two kinds of special side-chain functional groups is demonstrated. One of the side-chain groups provides emissive properties, while the other serves as the ligand unit. The copolymers are used to prepare a new kind of CdTe nanocrystal-based semiconductor nanocomposite. Their structures and morphologies are characterized and their optoelectronic properties are studied. The results reveal that an energy-transfer process from the emissive random copolymers to the CdTe nanocrystals occurs, while a photoinduced charge transfer is estimated to be thermodynamically forbidden. 2012-09-18T09:15:03Z 2019-12-06T18:48:35Z 2012-09-18T09:15:03Z 2019-12-06T18:48:35Z 2007 2007 Journal Article Qi, X. Y., Pu, K. Y., Fang, C., Wen, G. A., Zhang, H., Boey, F. Y. C., et al. (2007). Semiconductor nanocomposites of emissive flexible random copolymers and CdTe nanocrystals : preparation, characterization, and optoelectronic properties. Macromolecular Chemistry and Physics, 208(18), 2007-2017. 1521-3935 https://hdl.handle.net/10356/93967 http://hdl.handle.net/10220/8566 10.1002/macp.200700088 en Macromolecular chemistry and physics © 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
spellingShingle | DRNTU::Engineering::Materials Qi, Xiaoying Pu, Kan-Yi Fang, Chun Wen, Gui-An Zhang, Hua Boey, Freddy Yin Chiang Fan, Qu-Li Wang, Lianhui Huang, Wei Semiconductor nanocomposites of emissive flexible random copolymers and CdTe nanocrystals : preparation, characterization, and optoelectronic properties |
title | Semiconductor nanocomposites of emissive flexible random copolymers and CdTe nanocrystals : preparation, characterization, and optoelectronic properties |
title_full | Semiconductor nanocomposites of emissive flexible random copolymers and CdTe nanocrystals : preparation, characterization, and optoelectronic properties |
title_fullStr | Semiconductor nanocomposites of emissive flexible random copolymers and CdTe nanocrystals : preparation, characterization, and optoelectronic properties |
title_full_unstemmed | Semiconductor nanocomposites of emissive flexible random copolymers and CdTe nanocrystals : preparation, characterization, and optoelectronic properties |
title_short | Semiconductor nanocomposites of emissive flexible random copolymers and CdTe nanocrystals : preparation, characterization, and optoelectronic properties |
title_sort | semiconductor nanocomposites of emissive flexible random copolymers and cdte nanocrystals preparation characterization and optoelectronic properties |
topic | DRNTU::Engineering::Materials |
url | https://hdl.handle.net/10356/93967 http://hdl.handle.net/10220/8566 |
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