Self-assembled shape- and orientation-controlled synthesis of nanoscale Cu3Si triangles, squares, and wires

Controlling shape and orientation is important for the synthesis of functional nanomaterials. In this work, nanoscale Cu3Si triangles, squares, and wires have been grown on Si(111), (100), and (110) substrates, respectively, through a template-free Au-nanoparticle-assisted vapor transport method. Th...

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Hauptverfasser: Wang, Junling, Zhang, Zhou, Wong, Lai Mun, Ong, Hock Guan, Wang, Xin Jiao, Wang, Shijie, Chen, Hongyu, Wu, Tom
Weitere Verfasser: School of Materials Science & Engineering
Format: Journal Article
Sprache:English
Veröffentlicht: 2011
Schlagworte:
Online Zugang:https://hdl.handle.net/10356/94524
http://hdl.handle.net/10220/7424
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author Wang, Junling
Zhang, Zhou
Wong, Lai Mun
Ong, Hock Guan
Wang, Xin Jiao
Wang, Shijie
Chen, Hongyu
Wu, Tom
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Wang, Junling
Zhang, Zhou
Wong, Lai Mun
Ong, Hock Guan
Wang, Xin Jiao
Wang, Shijie
Chen, Hongyu
Wu, Tom
author_sort Wang, Junling
collection NTU
description Controlling shape and orientation is important for the synthesis of functional nanomaterials. In this work, nanoscale Cu3Si triangles, squares, and wires have been grown on Si(111), (100), and (110) substrates, respectively, through a template-free Au-nanoparticle-assisted vapor transport method. The sides of nanotriangles and nanosquares and the growth direction of the nanowires are all along Si 110, giving rise to long-range ordering of the nanostructures. Au nanoparticles absorb Cu vapor and facilitate the rate-limited diffusion of Si, which is critical for the shape-controlled growth of Cu3Si. This bottom-up approach to synthesize shape- and orientation-controlled Cu3Si nanostructures might be applicable to the tailored growth of other materials.
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spelling ntu-10356/945242020-06-01T10:21:28Z Self-assembled shape- and orientation-controlled synthesis of nanoscale Cu3Si triangles, squares, and wires Wang, Junling Zhang, Zhou Wong, Lai Mun Ong, Hock Guan Wang, Xin Jiao Wang, Shijie Chen, Hongyu Wu, Tom School of Materials Science & Engineering DRNTU::Engineering::Materials::Nanostructured materials Controlling shape and orientation is important for the synthesis of functional nanomaterials. In this work, nanoscale Cu3Si triangles, squares, and wires have been grown on Si(111), (100), and (110) substrates, respectively, through a template-free Au-nanoparticle-assisted vapor transport method. The sides of nanotriangles and nanosquares and the growth direction of the nanowires are all along Si 110, giving rise to long-range ordering of the nanostructures. Au nanoparticles absorb Cu vapor and facilitate the rate-limited diffusion of Si, which is critical for the shape-controlled growth of Cu3Si. This bottom-up approach to synthesize shape- and orientation-controlled Cu3Si nanostructures might be applicable to the tailored growth of other materials. Accepted version 2011-12-20T04:37:43Z 2019-12-06T18:57:25Z 2011-12-20T04:37:43Z 2019-12-06T18:57:25Z 2008 2008 Journal Article Zhang, Z., Wong, L. M., Ong, H. G., Wang, X., Wang, J., Wang, S., & et al. (2008). Self-assembled shape- and orientation- controlled synthesis of nanoscale Cu3Si triangles, squares, and wires. Nano Letters, 8(10), 3205-3210. https://hdl.handle.net/10356/94524 http://hdl.handle.net/10220/7424 10.1021/nl8015208 en Nano letters © 2008 American Chemical Society.
spellingShingle DRNTU::Engineering::Materials::Nanostructured materials
Wang, Junling
Zhang, Zhou
Wong, Lai Mun
Ong, Hock Guan
Wang, Xin Jiao
Wang, Shijie
Chen, Hongyu
Wu, Tom
Self-assembled shape- and orientation-controlled synthesis of nanoscale Cu3Si triangles, squares, and wires
title Self-assembled shape- and orientation-controlled synthesis of nanoscale Cu3Si triangles, squares, and wires
title_full Self-assembled shape- and orientation-controlled synthesis of nanoscale Cu3Si triangles, squares, and wires
title_fullStr Self-assembled shape- and orientation-controlled synthesis of nanoscale Cu3Si triangles, squares, and wires
title_full_unstemmed Self-assembled shape- and orientation-controlled synthesis of nanoscale Cu3Si triangles, squares, and wires
title_short Self-assembled shape- and orientation-controlled synthesis of nanoscale Cu3Si triangles, squares, and wires
title_sort self assembled shape and orientation controlled synthesis of nanoscale cu3si triangles squares and wires
topic DRNTU::Engineering::Materials::Nanostructured materials
url https://hdl.handle.net/10356/94524
http://hdl.handle.net/10220/7424
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