Probing carboxylic acid groups in replaced and mixed self-assembled monolayers by individual ionized dendrimer molecules : an atomic force microscopy study
Polyphenylene dendrimer molecules, G2Td(COOH)16, were ionized (G2 ions) and then adsorbed on a carboxylic acid (COOH) group terminated self-assembled monolayer (SAM) on a Au substrate through the linkage with Cu2+ ions. The individual G2 ions were observed by noncontact atomic force microscopy (NCAF...
| Main Authors: | , , , , , , , , , , |
|---|---|
| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2012
|
| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/95392 http://hdl.handle.net/10220/8549 |
| _version_ | 1826129867685494784 |
|---|---|
| author | Wiesler, U. M. Grim, P. C. M. Vosch, T. Berresheim, A. J. Müllen, K. Van Haesendonck, C. Vandamme, N. De Schryver, F. C. Zhang, Hua Liu, Daojun De Feyter, Steven |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Wiesler, U. M. Grim, P. C. M. Vosch, T. Berresheim, A. J. Müllen, K. Van Haesendonck, C. Vandamme, N. De Schryver, F. C. Zhang, Hua Liu, Daojun De Feyter, Steven |
| author_sort | Wiesler, U. M. |
| collection | NTU |
| description | Polyphenylene dendrimer molecules, G2Td(COOH)16, were ionized (G2 ions) and then adsorbed on a carboxylic acid (COOH) group terminated self-assembled monolayer (SAM) on a Au substrate through the linkage with Cu2+ ions. The individual G2 ions were observed by noncontact atomic force microscopy (NCAFM). The strong interaction between the G2 and Cu2+ ions, the latter of which are preadsorbed on the COOH SAM, led to a compression or deformation of the SAM and resulted in a decreased height of the G2 ions measured by NCAFM as compared to a theoretical model of the dendrimer molecules. The present method offers an approach to bind dendrimer molecules to a solid substrate and to study the nanoscale behavior of two kinds of thiol molecules in replaced and mixed SAMs. |
| first_indexed | 2024-10-01T07:47:33Z |
| format | Journal Article |
| id | ntu-10356/95392 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T07:47:33Z |
| publishDate | 2012 |
| record_format | dspace |
| spelling | ntu-10356/953922020-06-01T10:21:20Z Probing carboxylic acid groups in replaced and mixed self-assembled monolayers by individual ionized dendrimer molecules : an atomic force microscopy study Wiesler, U. M. Grim, P. C. M. Vosch, T. Berresheim, A. J. Müllen, K. Van Haesendonck, C. Vandamme, N. De Schryver, F. C. Zhang, Hua Liu, Daojun De Feyter, Steven School of Materials Science & Engineering DRNTU::Engineering::Materials Polyphenylene dendrimer molecules, G2Td(COOH)16, were ionized (G2 ions) and then adsorbed on a carboxylic acid (COOH) group terminated self-assembled monolayer (SAM) on a Au substrate through the linkage with Cu2+ ions. The individual G2 ions were observed by noncontact atomic force microscopy (NCAFM). The strong interaction between the G2 and Cu2+ ions, the latter of which are preadsorbed on the COOH SAM, led to a compression or deformation of the SAM and resulted in a decreased height of the G2 ions measured by NCAFM as compared to a theoretical model of the dendrimer molecules. The present method offers an approach to bind dendrimer molecules to a solid substrate and to study the nanoscale behavior of two kinds of thiol molecules in replaced and mixed SAMs. 2012-09-14T06:37:12Z 2019-12-06T19:13:58Z 2012-09-14T06:37:12Z 2019-12-06T19:13:58Z 2002 2002 Journal Article Zhang, H., Grim, P. C. M., Liu, D., Vosch, T., De Feyter, S., Wiesler, U. M., et al. (2002). Probing carboxylic acid groups in replaced and mixed self-assembled monolayers by individual ionized dendrimer molecules : an atomic force microscopy study. Langmuir, 18(5), 1801-1810. 0743-7463 https://hdl.handle.net/10356/95392 http://hdl.handle.net/10220/8549 10.1021/la011061t en Langmuir © 2002 American Chemical Society. |
| spellingShingle | DRNTU::Engineering::Materials Wiesler, U. M. Grim, P. C. M. Vosch, T. Berresheim, A. J. Müllen, K. Van Haesendonck, C. Vandamme, N. De Schryver, F. C. Zhang, Hua Liu, Daojun De Feyter, Steven Probing carboxylic acid groups in replaced and mixed self-assembled monolayers by individual ionized dendrimer molecules : an atomic force microscopy study |
| title | Probing carboxylic acid groups in replaced and mixed self-assembled monolayers by individual ionized dendrimer molecules : an atomic force microscopy study |
| title_full | Probing carboxylic acid groups in replaced and mixed self-assembled monolayers by individual ionized dendrimer molecules : an atomic force microscopy study |
| title_fullStr | Probing carboxylic acid groups in replaced and mixed self-assembled monolayers by individual ionized dendrimer molecules : an atomic force microscopy study |
| title_full_unstemmed | Probing carboxylic acid groups in replaced and mixed self-assembled monolayers by individual ionized dendrimer molecules : an atomic force microscopy study |
| title_short | Probing carboxylic acid groups in replaced and mixed self-assembled monolayers by individual ionized dendrimer molecules : an atomic force microscopy study |
| title_sort | probing carboxylic acid groups in replaced and mixed self assembled monolayers by individual ionized dendrimer molecules an atomic force microscopy study |
| topic | DRNTU::Engineering::Materials |
| url | https://hdl.handle.net/10356/95392 http://hdl.handle.net/10220/8549 |
| work_keys_str_mv | AT wieslerum probingcarboxylicacidgroupsinreplacedandmixedselfassembledmonolayersbyindividualionizeddendrimermoleculesanatomicforcemicroscopystudy AT grimpcm probingcarboxylicacidgroupsinreplacedandmixedselfassembledmonolayersbyindividualionizeddendrimermoleculesanatomicforcemicroscopystudy AT voscht probingcarboxylicacidgroupsinreplacedandmixedselfassembledmonolayersbyindividualionizeddendrimermoleculesanatomicforcemicroscopystudy AT berresheimaj probingcarboxylicacidgroupsinreplacedandmixedselfassembledmonolayersbyindividualionizeddendrimermoleculesanatomicforcemicroscopystudy AT mullenk probingcarboxylicacidgroupsinreplacedandmixedselfassembledmonolayersbyindividualionizeddendrimermoleculesanatomicforcemicroscopystudy AT vanhaesendonckc probingcarboxylicacidgroupsinreplacedandmixedselfassembledmonolayersbyindividualionizeddendrimermoleculesanatomicforcemicroscopystudy AT vandammen probingcarboxylicacidgroupsinreplacedandmixedselfassembledmonolayersbyindividualionizeddendrimermoleculesanatomicforcemicroscopystudy AT deschryverfc probingcarboxylicacidgroupsinreplacedandmixedselfassembledmonolayersbyindividualionizeddendrimermoleculesanatomicforcemicroscopystudy AT zhanghua probingcarboxylicacidgroupsinreplacedandmixedselfassembledmonolayersbyindividualionizeddendrimermoleculesanatomicforcemicroscopystudy AT liudaojun probingcarboxylicacidgroupsinreplacedandmixedselfassembledmonolayersbyindividualionizeddendrimermoleculesanatomicforcemicroscopystudy AT defeytersteven probingcarboxylicacidgroupsinreplacedandmixedselfassembledmonolayersbyindividualionizeddendrimermoleculesanatomicforcemicroscopystudy |