Direct observation of inner and outer Gʹ band double-resonance Raman scattering in free standing graphene

In contrary to the widely reported single and symmetric peak feature of G′ band in Raman spectrum of graphene, we herein report the observation of splitting in G′ band in free standing graphene. Our experimental findings provide a direct and strong support for the previous theoretical prediction tha...

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Main Authors: Luo, Zhiqiang, Cong, Chunxiao, Zhang, Jun, Xiong, Qihua, Yu, Ting
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2013
Subjects:
Online Access:https://hdl.handle.net/10356/95473
http://hdl.handle.net/10220/9296
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author Luo, Zhiqiang
Cong, Chunxiao
Zhang, Jun
Xiong, Qihua
Yu, Ting
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Luo, Zhiqiang
Cong, Chunxiao
Zhang, Jun
Xiong, Qihua
Yu, Ting
author_sort Luo, Zhiqiang
collection NTU
description In contrary to the widely reported single and symmetric peak feature of G′ band in Raman spectrum of graphene, we herein report the observation of splitting in G′ band in free standing graphene. Our experimental findings provide a direct and strong support for the previous theoretical prediction that the coexistence of the outer and inner processes in the double-resonance Raman scattering would cause the splitting of G′ mode. The investigation of the influence of trigonal warping effect on the spectral features of G′ subbands further verified the theoretical interpretation established on the anisotropic electronic structure of graphene.
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spelling ntu-10356/954732023-02-28T19:24:25Z Direct observation of inner and outer Gʹ band double-resonance Raman scattering in free standing graphene Luo, Zhiqiang Cong, Chunxiao Zhang, Jun Xiong, Qihua Yu, Ting School of Physical and Mathematical Sciences DRNTU::Science::Physics In contrary to the widely reported single and symmetric peak feature of G′ band in Raman spectrum of graphene, we herein report the observation of splitting in G′ band in free standing graphene. Our experimental findings provide a direct and strong support for the previous theoretical prediction that the coexistence of the outer and inner processes in the double-resonance Raman scattering would cause the splitting of G′ mode. The investigation of the influence of trigonal warping effect on the spectral features of G′ subbands further verified the theoretical interpretation established on the anisotropic electronic structure of graphene. Published version 2013-02-28T04:33:48Z 2019-12-06T19:15:37Z 2013-02-28T04:33:48Z 2019-12-06T19:15:37Z 2012 2012 Journal Article Luo, Z., Cong, C., Zhang, J., Xiong, Q., & Yu, T. (2012). Direct observation of inner and outer Gʹ band double-resonance Raman scattering in free standing graphene. Applied Physics Letters, 100(24), 243107-. 0003-6951 https://hdl.handle.net/10356/95473 http://hdl.handle.net/10220/9296 10.1063/1.4729407 en Applied physics letters © 2012 American Institute of Physics. This paper was published in Applied Physics Letters and is made available as an electronic reprint (preprint) with permission of American Institute of Physics. The paper can be found at the following official DOI: [http://dx.doi.org/10.1063/1.4729407]. One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper is prohibited and is subject to penalties under law. application/pdf
spellingShingle DRNTU::Science::Physics
Luo, Zhiqiang
Cong, Chunxiao
Zhang, Jun
Xiong, Qihua
Yu, Ting
Direct observation of inner and outer Gʹ band double-resonance Raman scattering in free standing graphene
title Direct observation of inner and outer Gʹ band double-resonance Raman scattering in free standing graphene
title_full Direct observation of inner and outer Gʹ band double-resonance Raman scattering in free standing graphene
title_fullStr Direct observation of inner and outer Gʹ band double-resonance Raman scattering in free standing graphene
title_full_unstemmed Direct observation of inner and outer Gʹ band double-resonance Raman scattering in free standing graphene
title_short Direct observation of inner and outer Gʹ band double-resonance Raman scattering in free standing graphene
title_sort direct observation of inner and outer g band double resonance raman scattering in free standing graphene
topic DRNTU::Science::Physics
url https://hdl.handle.net/10356/95473
http://hdl.handle.net/10220/9296
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